Comparative Study of Supported Monometallic Catalysts in the Liquid-Phase Hydrogenation of Furfural: Batch Versus Continuous Flow

被引：72

作者：

Wang, Yantao ^{[1
]}

Prinsen, Pepijn ^{[2
]}

Triantafyllidis, Konstantinos S. ^{[3
,4
]}

Karakoulia, Stamatia A. ^{[4
]}

Trikalitis, Pantelis N. ^{[5
]}

Yepez, A. ^{[2
]}

Len, Christophe ^{[1
,6
]}

Luque, Rafael ^{[2
,7
]}

机构：

[1] Univ Technol Compiegne, Sorbonne Univ, Ctr Rech Royallieu, CS 60319, F-60203 Compiegne, France

[2] Univ Cordoba, Dept Quim Organ, Campus Rabanales,Edificio Marie Curie,C-3, E-14014 Cordoba, Spain

[3] Aristotle Univ Thessaloniki, Dept Chem, Univ Campus,POB 116, GR-54124 Thessaloniki, Greece

[4] CERTH, Chem Proc & Energy Resources Inst, Thermi Rd,POB 60361, GR-57001 Thessaloniki, Greece

[5] Univ Crete Voutes, Dept Chem, Iraklion 71003, Greece

[6] PSL Res Univ, Inst Rech Chim Paris, CNRS, Chim ParisTech, 11 Rue Pierre & Marie Curie, F-75231 Paris 05, France

[7] RUDN Univ, Peoples Friendship Univ Russia, 6 Miklukho Maklaya Str 7, Moscow 117198, Russia

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 08期

关键词：

Furfural; Hydrogenation; Monometallic carbon-supported catalysts; Methylfuran; Batch; Continuous flow; HIGHLY SELECTIVE HYDROGENATION; LIGNOCELLULOSIC BIOMASS; ALCOHOL; PRETREATMENT; LIGNIN; TECHNOLOGIES; CHEMICALS; ACID; 2-METHYLFURAN; NANOPARTICLES;

D O I：

10.1021/acssuschemeng.8b00984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work compares the catalytic performance of well-defined monometallic catalysts supported on commercial microporous/mesoporous carbon (Cu/AC, Pd/AC, Pt/AC, and Ni/AC) for the liquid-phase hydrogenation of furfural, both in batch and in continuous flow. Whereas Ni/AC performed better in batch (in terms of selectivity to 2-methylfuran), better results were obtained with Pt/AC in continuous flow. Reutilization of the Ni/AC catalyst recovered by simple filtration after batch experiments changed the selectivity from 2-methylfuran to furfuryl alcohol. The solvent type and the reaction conditions were essential for the catalytic performance. Metal leaching was the main cause of catalyst deactivation.

引用

页码：9831 / 9844

页数：27

共 46 条

[1] Pd-Ru/TiO2 catalyst - an active and selective catalyst for furfural hydrogenation [J].

Aldosari, Obaid F. ;

Iqbal, Sarwat ;

Miedziak, Peter J. ;

Brett, Gemma L. ;

Jones, Daniel R. ;

Liu, Xi ;

Edwards, Jennifer K. ;

Morgan, David J. ;

Knight, David K. ;

Hutchings, Graham J. .

CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (01) :234-242

[2]

[Anonymous], 2004, MODERN PRACTICE GAS, DOI DOI 10.1002/0471651141

[3] Mechanical pretreatments of lignocellulosic biomass: towards facile and environmentally sound technologies for biofuels production [J].

Barakat, Abdellatif ;

Mayer-Laigle, Claire ;

Solhy, Abderrahim ;

Arancon, Rick A. D. ;

de Vries, Hugo ;

Luque, Rafael .

RSC ADVANCES, 2014, 4 (89) :48109-48127

[4] Tailoring the Product Distribution with Batch and Continuous Process Options in Catalytic Hydrogenation of Furfural [J].

Biradar, Narayan S. ;

Hengne, Amol A. ;

Birajdar, Shobha N. ;

Swami, Rameshwar ;

Rode, Chandrashekhar V. .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2014, 18 (11) :1434-1442

[5] Deconstruction of lignocellulosic biomass with ionic liquids [J].

Brandt, Agnieszka ;

Grasvik, John ;

Hallett, Jason P. ;

Welton, Tom .

GREEN CHEMISTRY, 2013, 15 (03) :550-583

[6] Mechanocatalytic Depolymerization of Dry (Ligno)cellulose As an Entry Process for High-Yield Production of Furfurals [J].

Carrasquillo-Flores, Ronald ;

Kaeldstroem, Mats ;

Schueth, Ferdi ;

Dumesic, James A. ;

Rinaldi, Roberto .

ACS CATALYSIS, 2013, 3 (05) :993-997

[7] Reductive amination of furfural to furfurylamine using aqueous ammonia solution and molecular hydrogen: an environmentally friendly approach [J].

Chatterjee, Maya ;

Ishizaka, Takayuki ;

Kawanami, Hajime .

GREEN CHEMISTRY, 2016, 18 (02) :487-496

[8] Tuning catalytic selectivity of liquid-phase hydrogenation of furfural via synergistic effects of supported bimetallic catalysts [J].

Chen, Bingfeng ;

Li, Fengbo ;

Huang, Zhijun ;

Yuan, Guoqing .

APPLIED CATALYSIS A-GENERAL, 2015, 500 :23-29

[9] Experimental study for liquid phase selective hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on supported Ni catalysts [J].

Chen, Xiaochun ;

Sun, Wei ;

Xiao, Nan ;

Yan, Yanjiao ;

Liu, Shiwei .

CHEMICAL ENGINEERING JOURNAL, 2007, 126 (01) :5-11

[10] Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water [J].

Chen, Xiufang ;

Zhang, Ligang ;

Zhang, Bo ;

Guo, Xingcui ;

Mu, Xindong .

SCIENTIFIC REPORTS, 2016, 6

← 1 2 3 4 5 →