Self-Optimizing Continuous Reactions in Supercritical Carbon Dioxide

被引:111
作者
Parrott, Andrew J. [1 ]
Bourne, Richard A. [1 ]
Akien, Geoffrey R. [1 ]
Irvine, Derek J. [1 ,2 ]
Poliakoff, Martyn [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Nottingham, Dept Chem & Environm Engn, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
alkylation; heterogeneous catalysis; reaction optimization; supercritical fluids; sustainable chemistry; SUPER-MODIFIED SIMPLEX; DIMETHYL CARBONATE; OPTIMIZATION; DEHYDRATION; ALCOHOLS; ALUMINA; SYSTEM; ETHER; ACID; CO2;
D O I
10.1002/anie.201100412
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hands-free optimization: A combination of an automated flow reactor, online analysis, and a control algorithm leads to efficient optimization of reactions to a given product without the need for human intervention. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3788 / 3792
页数:5
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