Bis{1-[3-(diethylammonio)propyliminomethyl]naphthalen-2-olato}nickel(II) dinitrate

被引:2
作者
Ji, Xiao-Hui [1 ]
Lu, Jiu-Fu [1 ]
机构
[1] Shaanxi Univ Technol, Sch Chem & Environm Sci, Hanzhong 723000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
CRYSTAL-STRUCTURES; COMPLEXES; COPPER(II); ZINC(II); LIGAND;
D O I
10.1107/S1600536810025663
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Ni(C18H24N2O)(2)](NO3)(2), consists of one half of the centrosymmetric nickel(II) complex cation and a nitrate anion. The NiII atom, lying on an inversion center, is four-coordinated by the phenolate O atoms and imine N atoms of two Schiff base ligands, forming a square-planar geometry. The O- and N-donor atoms are mutually trans. In the crystal structure, the nitrate anions are linked to the complex cations by intermolecular N-H...O hydrogen bonds.
引用
收藏
页码:M883 / U260
页数:11
相关论文
共 14 条
  • [1] Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystal structure, and magnetic study
    Adhikary, Chandan
    Sen, Rupam
    Bocelli, Gabriele
    Cantoni, Andrea
    Solzi, Massimo
    Chaudhuri, Siddhartha
    Koner, Subratanath
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (22) : 3573 - 3582
  • [2] [Anonymous], 2004, APEX2 SAINT
  • [3] BIS(N-CYCLOHEXYLSALICYLIDENEAMINATO)NICKEL(II), [NI(C13H16NO)2]
    BHATIA, SC
    SYAL, VK
    KASHYAP, RP
    JAIN, PC
    BROWN, CJ
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (FEB) : 199 - 200
  • [4] Synthesis of neutral nickel catalysts for ethylene polymerization - the influence of ligand size on catalyst stability
    Connor, EF
    Younkin, TR
    Henderson, JI
    Waltman, AW
    Grubbs, RH
    [J]. CHEMICAL COMMUNICATIONS, 2003, (18) : 2272 - 2273
  • [5] Synthesis and Crystal Structures of Two Schiff Bases of 2-(Methylthio) aniline with Halogenated Salicylaldehydes
    Hamaker, Christopher G.
    Maryashina, Oksana S.
    Daley, Dana K.
    Wadler, Andrew L.
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (01) : 34 - 39
  • [6] STRUCTURES OF 3 BIS(3-ETHOXY-N-R-SALICYLIDENEAMINATO)NICKEL(II) COMPLEXES (R = H, METHYL, ETHYL)
    KAMENAR, B
    KAITNER, B
    STEFANOVIC, A
    WATERS, TN
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1990, 46 : 1627 - 1631
  • [7] Synthesis and characterization of nickel(II) complexes with three potentially hexadentate Schiff-base ligands and polyamines: X-ray crystal structure determination of one nickel(II) complex
    Keypour, Hassan
    Azadbakht, Reza
    Rudbari, Hadi Amiri
    Heydarinekoo, Alireza
    Khavasi, Hamidreza
    [J]. TRANSITION METAL CHEMISTRY, 2009, 34 (08) : 835 - 839
  • [8] Synthesis, crystal structures, and molecular hyperpolarizabilities of a new Schiff base ligand, and its copper(II), nickel(II), and cobalt(II) metal complexes
    Lacroix, PG
    Averseng, F
    Malfant, I
    Nakatani, K
    [J]. INORGANICA CHIMICA ACTA, 2004, 357 (13) : 3825 - 3835
  • [9] Crystal structures, antioxidation and DNA binding properties of Dy(III) complexes with Schiff-base ligands derived from 8-hydroxyquinoline-2-carboxaldehyde and four aroylhydrazines
    Liu, Yong-chun
    Yang, Zheng-yin
    [J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2009, 44 (12) : 5080 - 5089
  • [10] Synthesis, spectroscopic studies and crystal structures of ReI(CO)3(NN)Cl complexes with N,N'-bis(substituted benzylidene)ethane-1,2-diamine Schiff base ligands
    Mirkhani, Valiollah
    Kia, Reza
    Milic, Dalibor
    Vartooni, Akbar Rostami
    Matkovic-Calogovic, Dubravka
    [J]. TRANSITION METAL CHEMISTRY, 2010, 35 (01) : 81 - 87