Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography

被引：24
|
作者：
Nastasovic, AB
Onjia, AE
Milonjic, SK
Jovanovic, SM
机构：
[1] Ctr Chem, Inst Chem Technol & Met, YU-11001 Belgrade, Serbia Monteneg, Serbia
[2] Vinca Inst Nucl Sci, Chem Dynam Lab, YU-11001 Belgrade, Serbia Monteneg, Serbia
[3] Fac Technol & Met Belgrade, YU-11001 Belgrade, Serbia Monteneg, Serbia
来源：
EUROPEAN POLYMER JOURNAL | 2005年 / 41卷 / 06期
关键词：
thermodynamic parameters; adsorption; inverse gas chromatography; glycidyl methacrylate based copolymers;
D O I：
10.1016/j.eurpolymj.2004.12.020
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, with different porosity parameters were synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine, EDA. Inverse gas chromatography at infinite dilution was used for the determination of adsorption properties of PGME, and copolymer modified with ethylene diamine, PGME-en. Thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the S, acid/base constants for the copolymer samples were calculated. The calculated dispersive surface energy values, gamma(d)(S), for PGME and PGME-en are comparable with the literature data for nonconductive polymers. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：1234 / 1242
页数：9
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