Catalytic Intermolecular Dicarbofunctionalization of Styrenes with CO2 and Radical Precursors

被引：231

作者：

Reddy Yatham, Veera ^{[1
]}

Shen, Yangyang ^{[1
]}

Martin, Ruben ^{[1
,2
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Ave Paisos Catalans 16, Tarragona 43007, Spain

[2] ICREA, Passeig Lluis Companys 23, Barcelona 08010, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 36期

基金：

欧洲研究理事会;

关键词：

iridium; photochemistry; radicals; reaction mechanisms; synthetic methods; VISIBLE-LIGHT PHOTOREDOX; C-H BONDS; SINGLE-ELECTRON TRANSMETALATION; TRANSITION-METAL-FREE; CARBON-DIOXIDE; DIRECT CARBOXYLATION; REDUCTIVE CARBOXYLATION; UNACTIVATED PRIMARY; ORGANIC-SYNTHESIS; NICKEL CATALYSIS;

D O I：

10.1002/anie.201706263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A redox-neutral intermolecular dicarbofunctionalization of styrenes with CO2 at atmospheric pressure and carbon-centered radicals is described. This mild protocol results in multiple C-C bond-forming reactions from simple precursors in the absence of stoichiometric reductants, thus exploiting a previously unrecognized opportunity that complements existing catalytic carboxylation events.

引用

页码：10915 / 10919

页数：5

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