Catalytic Intermolecular Dicarbofunctionalization of Styrenes with CO2 and Radical Precursors

被引：236

作者：

Reddy Yatham, Veera ^{[1
]}

Shen, Yangyang ^{[1
]}

Martin, Ruben ^{[1
,2
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Ave Paisos Catalans 16, Tarragona 43007, Spain

[2] ICREA, Passeig Lluis Companys 23, Barcelona 08010, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 36期

基金：

欧洲研究理事会;

关键词：

iridium; photochemistry; radicals; reaction mechanisms; synthetic methods; VISIBLE-LIGHT PHOTOREDOX; C-H BONDS; SINGLE-ELECTRON TRANSMETALATION; TRANSITION-METAL-FREE; CARBON-DIOXIDE; DIRECT CARBOXYLATION; REDUCTIVE CARBOXYLATION; UNACTIVATED PRIMARY; ORGANIC-SYNTHESIS; NICKEL CATALYSIS;

D O I：

10.1002/anie.201706263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A redox-neutral intermolecular dicarbofunctionalization of styrenes with CO2 at atmospheric pressure and carbon-centered radicals is described. This mild protocol results in multiple C-C bond-forming reactions from simple precursors in the absence of stoichiometric reductants, thus exploiting a previously unrecognized opportunity that complements existing catalytic carboxylation events.

引用

页码：10915 / 10919

页数：5

共 89 条

[1]

[Anonymous], 2011, ANGEW CHEM-GER EDIT

[2]

[Anonymous], 2004, Metal-Catalyzed Cross-Coupling Reactions

[3]

[Anonymous], 2012, ANGEW CHEM, V124, P12469

[4]

[Anonymous], 2011, ANGEW CHEM-GER EDIT

[5] Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2 [J].

Borjesson, Marino ;

Moragas, Toni ;

Gallego, Daniel ;

Martin, Ruben .

ACS CATALYSIS, 2016, 6 (10) :6739-6749

[6]

Börjesson M, 2016, J AM CHEM SOC, V138, P7504, DOI [10.1021/jacs.6b04088, 10.1021/jacs.6604088]

[7] Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N-Hydroxyphthalimide Esters [J].

Candish, Lisa ;

Teders, Michael ;

Glorius, Frank .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (22) :7440-7443

[8] One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis [J].

Carboni, Aude ;

Dagousset, Guillaume ;

Magnier, Emmanuel ;

Masson, Geraldine .

CHEMICAL COMMUNICATIONS, 2014, 50 (91) :14197-14200

[9]

Carry B., 2016, ANGEW CHEM, V128, P6365

[10] Synthesis of Lithium Boracarbonate Ion Pairs by Copper-Catalyzed Multi-Component Coupling of Carbon Dioxide, Diboron, and Aldehydes [J].

Carry, Beatrice ;

Zhang, Liang ;

Nishiura, Masayoshi ;

Hou, Zhaomin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (21) :6257-6260

← 1 2 3 4 5 6 7 8 9 →