Synthesis of aromatic thioamide from nitrile without handling of gaseous hydrogen sulfide

被引：52
|
作者：
Manaka, A [1 ]
Sato, M [1 ]
机构：
[1] Taisho Pharmaceut Co Ltd, Med Res Labs, Med Chem Lab, Kita Ku, Saitama, Saitama 3319530, Japan
来源：
SYNTHETIC COMMUNICATIONS | 2005年 / 35卷 / 05期
关键词：
thioamides; nitriles; magnesium chloride;
D O I：
10.1081/SCC-200050393
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method for synthesizing aromatic primary thioamides is described. Simple treatment of aromatic nitriles with sodium hydrogen sulfide and magnesium chloride in dimethylformamide (DMF) gave aromatic primary thioamides in yields of 80-99% without handling of hazardous hydrogen sulfide.
引用
收藏
页码：761 / 764
页数：4
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