Evaluation of the presence of major anionic surfactants in marine sediments

被引:16
作者
Cantarero, S. [1 ]
Camino-Sanchez, F. J. [1 ]
Zafra-Gomez, A. [1 ]
Ballesteros, O. [1 ]
Navalon, A. [1 ]
Vilchez, J. L. [1 ]
Verge, C. [2 ]
Reis, M. S. [3 ]
Saraiva, P. M. [3 ]
机构
[1] Univ Granada, Dept Analyt Chem, Fac Sci, E-18071 Granada, Spain
[2] Cepsa Quim SA, E-28042 Madrid, Spain
[3] Univ Coimbra, Dept Chem Engn, Coimbra, Portugal
关键词
Surfactants; Marine sediments; PCA; Liquid chromatography; Extraction techniques; LINEAR ALKYLBENZENE SULFONATES; ANAEROBIC DEGRADATION; LIQUID-CHROMATOGRAPHY; SEWAGE-SLUDGE; SOAP; BIODEGRADATION; WATER; LAS;
D O I
10.1016/j.marpolbul.2011.12.015
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The contamination of aquatic environments has become the focus of increasing regulation and public concern due to their potential and unknown negative effects on the ecosystems. The present work develops a monitoring and statistical study, based on the analysis of variance test (ANOVA) and the multivariable analysis, both for insoluble soap and LAS in order to compare the behavior of different anionic surfactants in this environmental compartment. First, a novel and successfully validated methodology to analyze insoluble soap in these samples is developed. The matrix effect and the comparison of different extraction techniques were also performed. The optimized analytical methodologies were applied to 48 representative samples collected from the Almeria Coast (Spain) and then a statistical analysis to correlate anionic surfactant concentration and several variables associated with marine sediment samples was also developed. The results obtained showed relevant conclusions related to the environmental behavior of anionic surfactants in marine sediments. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:587 / 594
页数:8
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