Quantitative evaluation of anion-π interactions in solution

被引：181

作者：

Gil-Ramirez, Guzman ^{[1
]}

Escudero-Adan, Eduardo C. ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Ballester, Pablo ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 22期

关键词：

anions; calixarenes; hydrogen bonds; Pi interactions; receptors;

D O I：

10.1002/anie.200800636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Anions included: A series of meso-tetraaryl calix[4]pyrrole receptors have been used as a model system to quantify chloride-π interactions in solution (see picture; green balls are chloride ions). The free energy values are generally indicative of a repulsive interaction; their magnitude depends on the substituent on the aromatic ring. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4114 / 4118

页数：5

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