Synthesis and tribological properties of diamond-like carbon films by electrochemical anode deposition

被引:16
作者
Li, Yang [1 ]
Zhang, GuiFeng [1 ]
Hou, XiaoDuo [1 ]
Deng, DeWei [1 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116024, Peoples R China
关键词
Diamond-like carbon; Anode deposition; Tribological property; AMORPHOUS-CARBON; ORGANIC LIQUIDS; RAMAN; ELECTROLYSIS; METHANOL; SPECTRA;
D O I
10.1016/j.apsusc.2012.03.070
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Diamond-like carbon films (DLC) are deposited on Ti substrate by electrochemical anodic deposition at room temperature in pure methanol solution using a pulsed DC voltage at a range from 200 V to 2000 V. Raman spectroscopy analysis of the films reveals two broaden characteristic absorption peaks centred at similar to 1350 cm(-1) and 1580 cm(-1), relating to D-and G-band of typical DLC films, respectively. A broad peak centred at 1325-1330 cm(-1) is observed when an applied potential is 1200 V, which can confirm that the deposited films contained diamond structure phase. Tribological properties of the coated Ti substrates have been measured by means of a ball-on-plate wear test machine. A related growth mechanism of DLC films by the anodic deposition mode has also been discussed. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:6527 / 6530
页数:4
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