An Electrocatalytic Newman-Kwart-type Rearrangement

被引：42

作者：

Broese, Timo ^{[1
]}

Roesel, Arend F. ^{[1
]}

Prudlik, Adrian ^{[1
]}

Francke, Robert ^{[1
]}

机构：

[1] Rostock Univ, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 23期

关键词：

THIOPHENOLS; CONVERSION; PHENOLS;

D O I：

10.1021/acs.orglett.8b03257

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An electrochemical approach toward rearrangement of O-aryl thiocarbamates to the corresponding S-aryl thiocarbamates is presented. The protocol requires only catalytic amounts of electric charge and allows for operation at room temperature. The electrolysis can be carried out with the simplest equipment, i.e., under galvanostatic conditions in an undivided cell. Furthermore, it is demonstrated that when the electrolysis is performed in a microflow reactor, almost quantitative yields can be achieved without using supporting electrolyte.

引用

页码：7483 / 7487

页数：5

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