Nickel N-heterocyclic carbene-pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water

被引：121

作者：

Thoi, V. Sara ^{[1
,2
,3
]}

Chang, Christopher J. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Howard Hughes Med Inst, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 23期

关键词：

ELECTROCHEMICAL REDUCTION; COPPER COMPLEX; CO2; REDUCTION; COBALT; PORPHYRINS; PHTHALOCYANINE; PHOTOREDUCTION; MACROCYCLES; CONVERSION; CATALYSIS;

D O I：

10.1039/c1cc10449g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a homologous series of nickel(II) complexes supported by N-heterocyclic carbene-pyridine ((R)bimpy, R = Me, Et, Pr) ligands that exhibit high selectivity for reducing carbon dioxide over water under electrocatalytic conditions.

引用

页码：6578 / 6580

页数：3

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