Synthesis and spark plasma sintering of the α-Si3N4 nanopowder

被引：6

作者：

Khajelakzay, Mohammad ^{[1
]}

Bakhshi, Saeed Reza ^{[1
]}

Borhani, Gholam Hossein ^{[1
]}

Ramazani, Mazaher ^{[1
]}

机构：

[1] Malek Ashtar Univ, Dept Mat Sci & Engn, Esfahan, Iran

来源：

CERAMICS INTERNATIONAL | 2016年 / 42卷 / 13期

关键词：

Silicon nitride; Two-step method; Nitridation; Mechanical alloying; Spark plasma sintering; SILICON-NITRIDE; MECHANICAL-PROPERTIES; PHASE-TRANSFORMATION; SI POWDERS; SI3N4; NANOWIRES; CERAMICS;

D O I：

10.1016/j.ceramint.2016.06.123

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A two-step process (milling and then heat treatment) was used for the preparation of alpha-Si3N4 nano powder. The influence of the milling time and heat treatment temperature as processing parameters were investigated on the formation of alpha-Si3N4. Silicon nitride ceramic was produced by spark plasma sintering at 1700 degrees C for 15 min, using MgSiN4 additive. The optimum sample was produced in a 30 h milling time, heat treatment at 1300 degrees C, and a 22 degrees C/min heating rate conditions. X-ray fluorescence analysis showed that the purity of the final product is above 98%. Nanoindentation hardness and Young's modulus of the SPS-ed sample were measured as 17 2.0 GPa and 290 +/- 11.0 GPa, respectively. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：14867 / 14872

页数：6

共 29 条

[1] HOT-PRESSING AND ALPHA-BETA PHASE-TRANSFORMATION IN SILICON-NITRIDE
BOWEN, LJ
WESTON, RJ
CARRUTHERS, TG
BROOK, RJ
[J]. JOURNAL OF MATERIALS SCIENCE, 1978, 13 (02) : 341 - 350
[2] Microstructure and mechanical properties of porous Si3N4-SiO2 ceramics fabricated by a process combining carbothermal reduction and sol-gel infiltration-sintering
Cai, Yaohui
Li, Xiangming
Dong, Jiahui
[J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2014, 601 : 111 - 115
[3] SYNTHESIS OF SILICON-NITRIDE BY MECHANICAL ALLOYING
CALKA, A
WILLIAMS, JS
MILLET, P
[J]. SCRIPTA METALLURGICA ET MATERIALIA, 1992, 27 (12): : 1853 - 1857
[4] CAMBIER F, 1990, NATO ADV SCI I E-APP, V185, P13
[5] Synthesis of α silicon nitride single-crystalline nanowires by nitriding cryomilled nanocrystalline silicon powder
Chen, Fei
Li, Ying
Liu, Wei
Shen, Qiang
Zhang, Lianmeng
Jiang, Qing
Lavernia, Enrique J.
Schoenung, Julie M.
[J]. SCRIPTA MATERIALIA, 2009, 60 (09) : 737 - 740
[6] MICROSTRUCTURES OF SILICON-NITRIDE CERAMICS DURING HOT-PRESSING TRANSFORMATIONS
DREW, P
LEWIS, MH
[J]. JOURNAL OF MATERIALS SCIENCE, 1974, 9 (02) : 261 - 269
[7] Halamka M, 2003, CERAM-SILIKATY, V47, P88
[8] Hampshire S, 2007, J ACHIEV MAT MANUF E, V24, P43
[9] Synthesis of silicon nitride nanorods using carbon nanotube as a template
Han, WQ
Fan, SS
Li, QQ
Gu, BL
Zhang, XB
Yu, DP
[J]. APPLIED PHYSICS LETTERS, 1997, 71 (16) : 2271 - 2273
[10] Ultra thin silicon nitride prepared by direct nitridation using ammonia decomposed species
Izumi, A
[J]. THIN SOLID FILMS, 2006, 501 (1-2) : 157 - 159

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