Synthesis of new pyridine silver(III) complexes

被引：1

作者：

Kahani, A ^{[1
]}

Abedini, M ^{[1
]}

Farnia, M ^{[1
]}

机构：

[1] Univ Tehran, Dept Chem, Tehran 141556455, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 53卷 / 01期

关键词：

pyridine; silver(III);

D O I：

10.1080/00958970108022595

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New pyridine silver(III) complexes have been synthesized by the concurrent oxidation of silver(I) ion and ammonia in the reaction of pyridine and silver nitrate using ammonium peroxydisulfate in aqueous ammonia solution. At high pH values, trans-[Ag(py)(2)(N-2)(2)](OH)(3) was obtained, which was then converted to trans-[Ag(py)(2)(N-2)(2)](ClO4)(3). However, at lower pH values [Ag(py)(4)](ClO4)(2)(NO3) was isolated.

引用

页码：1 / 6

页数：6

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