Total synthesis of (±)-crinine via the regioselective stille coupling and Diels-Alder reaction of 3,5-dibromo-2-pyrone

被引：54
作者：
Tam, Nguyen Thanh [1 ]
Cho, Cheon-Gyu [1 ]
机构：
[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 04期
关键词：
D O I：
10.1021/ol702907u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The regioselective synthesis and Diels-Alder cycloaddition of 3-(3,4-methylenedioxyphenyl)-5-bromo-2-pyrone provided a new synthetic route to crinine. The vinyl bromide group can be used as a handle for further derivatization.
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页码：601 / 603
页数：3
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