Generation and Diels-Alder reactions of t-butyl 2H-azirine-3-carboxylate

被引：31

作者：

Alves, MJ ^{[1
]}

Gilchrist, TL

机构：

[1] Univ Minho, Dept Quim, P-4710 Braga, Portugal

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(98)01617-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The azirinyl ester 2 (R = Bu-t) has been generated by thermolysis of t-butyl 2-azidoacrylate. It is too unstable to allow its full characterisation but it has been intercepted by Diels-Alder cycloaddition to several dienes. Addition to a chiral diene 8 is highly diastereoselective. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7579 / 7582

页数：4

共 14 条

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