Effect of decomposition of the Cr-Fe-Co rich phase of AlCoCrCuFeNi high entropy alloy on magnetic properties

被引:122
作者
Singh, S. [1 ]
Wanderka, N. [1 ]
Kiefer, K. [1 ]
Siemensmeyer, K. [1 ]
Banhart, J. [1 ]
机构
[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-14109 Berlin, Germany
关键词
High entropy alloys; TEM analysis; 3D-AP measurements; Magnetisation; SPINODAL DECOMPOSITION; MICROSTRUCTURE; SYSTEM;
D O I
10.1016/j.ultramic.2010.12.001
中图分类号
TH742 [显微镜];
学科分类号
摘要
Splat-quenched, as-cast and aged (2 h at 600 degrees C after casting) AlCoCrCuFeNi high entropy alloys were investigated by means of transmission electron microscopy and three-dimensional atom probe (3D-AP). 3D-AP revealed anti-correlated fluctuations of the Cr and Fe-Co compositions in Cr-Fe-Co-rich regions of the as-cast alloy. The ferromagnetic behavior of AlCoCrCuFeNi high entropy alloy was correlated with the decomposition of the Cr-Fe-Co-rich regions into ferromagnetic Fe-Co-rich and antiferromagnetic Cr-rich domains, the size of which was determined by statistical analysis of 3D-AP data. The splat-quenched alloy showed a softer magnetic behavior as compared to the as-cast and aged alloys. The aged alloy possessed a higher saturation magnetization and coercivity as compared to the as-cast alloy. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:619 / 622
页数:4
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