Isolation of two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands and their activities for functionalization of cyclohexane in the presence of hydrogen peroxide

被引：12

作者：

Ito, S

Okuno, T

Matsushima, H

Tokii, T

Nishida, Y

机构：

[1] YAMAGATA UNIV, FAC SCI, DEPT CHEM, YAMAGATA 990, JAPAN

[2] SAGA UNIV, FAC SCI & ENGN, DEPT CHEM, SAGA 840, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 21期

关键词：

D O I：

10.1039/dt9960004037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands were isolated and characterized by X-ray crystallography and their activities for cyclohexane functionalization in the presence of hydrogen peroxide examined.

引用

页码：4037 / 4039

页数：3

共 31 条

[21] (MU-OXO-HYDROXO)BIS(MU-CARBOXYLATO)DIIRON(III) AND DIMANGANESE(III) COMPLEXES WITH CAPPING TRIS(IMIDAZOL-2-YL)PHOSPHINE LIGANDS
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[22] STRUCTURAL AND ELECTRONIC-PROPERTIES OF TETRANUCLEAR IRON(III) PYRIDYLAMINE COMPLEXES CONTAINING COFACIAL PAIRS OF MU-OXO-BIS(MU-ACETATO)IRON(III) MOIETIES - MODELS FOR MET HEMERYTHRINS
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[23] (MU-OXO)BIS(MU-ACETATO)BIS(TRI-1-PYRAZOLYLBORATO)DIIRON-(III), [(HBPZ3)FEO(CH3CO2)2FE(HBPZ3)] - MODEL FOR THE BINUCLEAR IRON CENTER OF HEMERYTHRIN
ARMSTRONG, WH
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[24] DIOSMIUM(IV) COMPLEXES CONTAINING OXIDE AND CARBOXYLATE BRIDGES AND A WEAK OS-OS INTERACTION - STRUCTURE OF (MU-OXO)BIS(MU-ACETATO)BIS[DICHLORO(TRIPHENYLPHOSPHINE)OSMIUM(IV)] AS ITS DIETHYL-ETHER SOLVATE
ARMSTRONG, JE
ROBINSON, WR
WALTON, RA
INORGANIC CHEMISTRY, 1983, 22 (09) : 1301 - 1306
[25] RESONANCE-RAMAN SPECTRA AND EXCITED-STATE GEOMETRY OF THE BIS(MU-ACETATO)(MU-OXO) RUTHENIUM(III) DIMERIC ION [RU-2(MU-O(2)CME)(2)(MU-O)(PY)(6)](2+) (PY=PYRIDINE)
CIPRIANO, C
CLARK, RJH
OPRESCU, D
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (14): : 2417 - 2419
[26] (mu-oxo)bis(mu-carboxylato)bis(2,2'-bipyridyl)bis(X)diiron(III) complexes, X=NCS-, NCSe-, and N-3(-): Synthetic models of pseudohalide derivatives of carboxylate-bridged diiron proteins
Mizoguchi, TJ
Lippard, SJ
INORGANIC CHEMISTRY, 1997, 36 (20) : 4526 - 4533
[27] Model compounds for iron proteins. Structures and magnetic, spectroscopic, and redox properties of Fe(III)M(II) and [CoIIIFeIII](2)O complexes with (mu-carboxylato)bis(mu-phenoxo)dimetalate and (mu-oxo)diiron(III) cores
Dutta, SK
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Nanda, KK
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INORGANIC CHEMISTRY, 1996, 35 (08) : 2292 - 2300
[28] PREPARATION, STRUCTURE, AND PROPERTIES OF THE BIS(MU-ACETATO)(MU-OXO)RUTHENIUM(III) DIMERS [RU2(MU-CH3COO)2(MU-O)(PY)6]2+ AND [RU2(MU-CH3COO)2(MU-O)(BPY)2(PY)2]2+
SASAKI, Y
SUZUKI, M
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INORGANIC CHEMISTRY, 1991, 30 (26) : 4903 - 4908
[29] SYNTHESIS, CRYSTAL-STRUCTURES, MOSSBAUER, SUSCEPTIBILITY, AND EPR STUDIES OF A SERIES OF SPIN EXCHANGE COUPLED COMPLEXES CONTAINING THE (MU-OXO)BIS(MU-ACETATO)RUTHENIUMMETAL CORE AND ITS HYDROXO-BRIDGED ANALOG (METAL = V, CR, MN, FE, CO)
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) : 9470 - 9483
[30] First example of a rigid (mu-oxo-di-mu-acetato)diiron(III) complex with 1,2-bis[2-di(2-pyridyl)methyl-6-pyridyl]ethane; Its efficient catalysis for functionalization of alkanes
Kodera, M
Shimakoshi, H
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CHEMICAL COMMUNICATIONS, 1996, (15) : 1737 - 1738

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