Controllable preparation of ZnII coordination polymers:: unusual solvothermal formation of a LiGe-type framework directed by in situ S-S coupling of 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol

被引：42

作者：

Chen, Xu-Dong ^{[1
]}

Wu, Hui-Fang ^{[1
]}

Du, Miao ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300387, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 11期

关键词：

D O I：

10.1039/b716461k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled assembly of Zn-II with a versatile ligand 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol (Hptt) in conventional or solvothermal condition affords two distinct coordination frameworks, in which the former shows a unique 3-D pseudo-polyrotaxane architecture with 1-D water tapes penetrating the 2-D Zn-ptt layers, whereas the later is generated from in situ S-S coupling of Hptt and has a very rare 2-fold interpenetrating LiGe (lig) topology.

引用

页码：1296 / 1298

页数：3

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