2D Salphen-based heteropore covalent organic frameworks for highly efficient electrocatalytic water oxidation

被引:19
作者
Wang, Lin-Lin [1 ]
Zhang, Wen-Da [1 ]
Li, Tao [1 ]
Yan, Xiaodong [1 ]
Gao, Jie [1 ]
Chen, Yu-Xuan [1 ]
Shi, Ya-Xiang [1 ]
Gu, Zhi-Guo [1 ,2 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China
[2] Jiangnan Univ, Int Joint Res Ctr Photorespons Mol & Mat, Sch Chem & Mat Engn, Wuxi 214122, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
NANOSHEETS; CRYSTALLINE; POLYMERS;
D O I
10.1039/d1cc04369b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The construction of heteroporous covalent organic frameworks (COFs) is still a challenge. Herein, a series of 2D COFs with hexagonal and quadrilateral pores were constructed via in situ salphen or metal salphen formation. Metallized salphen-based COFs can be used as electrocatalysts towards water oxidation with an overpotential of 266 mV at 10 mA cm(-2).
引用
收藏
页码:13162 / 13165
页数:4
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