Photocatalytic properties of tungsten trioxide (WO3) nanoparticles for degradation of Lidocaine under visible and sunlight irradiation

被引:108
作者
Fakhri, Ali [1 ,2 ]
Behrouz, Sajjad [3 ]
机构
[1] Islamic Azad Univ, Dept Chem, Shahr E Qods Branch, Tehran, Iran
[2] Islamic Azad Univ, Young Researchers & Elite Club, Sci & Res Branch, Tehran, Iran
[3] Islamic Azad Univ, Cent Tehran Branch, Dept Biol, Tehran, Iran
关键词
WO3; nanoparticles; Photocatalytic activity; LDC; Sunlight; REMOVAL; LIGHT; WATER; TIO2;
D O I
10.1016/j.solener.2014.11.014
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Lidocaine (LDC) is a prevalent positional drug of anesthetic and found in aqueous environments as a pollutant due to its widespread use. The indiscriminate use of the chemicals leads to its release into the environment and it is a crucial ecological problem. The removal of pharmaceutical pollutants from industrial effluent is a difficult task. Many biological and physical techniques are being routinely used for removal of these pharmaceutical pollutants. The present study reports on the use of tungsten trioxide (WO3) nanoparticles for the degradation of LDC by making use of the photocatalytic property of NPs. WO3 NPs was synthesized and characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), UV-Visible (UV-Vis) spectroscopy and Brunauer-Emmett-Teller (BET) techniques. WO3 NPs showed a maximum photocatalytic effect at pH 6 and it degraded 95.48% and 97.5% of LDC within 1 h under visible and sunlight, respectively. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:163 / 168
页数:6
相关论文
共 20 条
[1]   Synthesis and characterization of WO3 spherical nanoparticles and nanorods [J].
Adhikari, Sangeeta ;
Sarkar, Debasish ;
Maiti, Himadri Sekhar .
MATERIALS RESEARCH BULLETIN, 2014, 49 :325-330
[2]   Photocatalytic activation of CdS NPs under visible light for environmental cleanup and disinfection [J].
Chandran, Preethy ;
Kumari, Pooja ;
Khan, S. Sudheer .
SOLAR ENERGY, 2014, 105 :542-547
[3]   Photocatalytic activity of metal oxides-The role of holes and OH• radicals [J].
Guo, Mu Yao ;
Ng, Alan Man Ching ;
Liu, Fangzhou ;
Djurisic, Aleksandra B. ;
Chan, Wai Kin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 107 (1-2) :150-157
[4]   Solar/TiO2 photocatalytic decomposition of β-blockers atenolol and propranolol in water and wastewater [J].
Ioannou, L. A. ;
Hapeshi, E. ;
Vasquez, M. I. ;
Mantzavinos, D. ;
Fatta-Kassinos, D. .
SOLAR ENERGY, 2011, 85 (09) :1915-1926
[5]   Removal of methylene blue dye aqueous solution using photocatalysis [J].
Joshi, K. M. ;
Shrivastava, V. S. .
INTERNATIONAL JOURNAL OF NANO DIMENSION, 2012, 2 (04) :241-252
[6]   Template-free synthesis of MgO nanoparticles for effective photocatalytic applications [J].
Mageshwari, K. ;
Mali, Sawanta S. ;
Sathyamoorthy, R. ;
Patil, Pramod S. .
POWDER TECHNOLOGY, 2013, 249 :456-462
[7]   OPTICAL AND ELECTRICAL-PROPERTIES OF SNO2 THIN-FILMS IN RELATION TO THEIR STOICHIOMETRIC DEVIATION AND THEIR CRYSTALLINE-STRUCTURE [J].
MANIFACIER, JC ;
DEMURCIA, M ;
FILLARD, JP ;
VICARIO, E .
THIN SOLID FILMS, 1977, 41 (02) :127-135
[8]   Microbial decolourisation and degradation of textile dyes [J].
McMullan, G ;
Meehan, C ;
Conneely, A ;
Kirby, N ;
Robinson, T ;
Nigam, P ;
Banat, IM ;
Marchant, R ;
Smyth, WE .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2001, 56 (1-2) :81-87
[9]   Dye-sensitized solar cells based on a single layer deposition of TiO2 from a new formulation paste and their photovoltaic performance [J].
Mohammadi, M. R. ;
Louca, R. R. M. ;
Fray, D. J. ;
Welland, M. E. .
SOLAR ENERGY, 2012, 86 (09) :2654-2664
[10]   Physical removal of textile dyes from effluents and solid-state fermentation of dye-adsorbed agricultural residues [J].
Nigam, P ;
Armour, G ;
Banat, IM ;
Singh, D ;
Marchant, R .
BIORESOURCE TECHNOLOGY, 2000, 72 (03) :219-226