A new three-dimensional. supramolecular network, [Cd(Hbic)2(H2O)]•(4,4'-bpy)•H2O (H2bic=1-H-benzimidazole-5carboxylic acid; 4,4-bpy=4,4'-bipyridine):: Synthesis, crystal structure and luminescence property

被引：27
作者：
Guo, Zhengang [1 ]
Li, Xiaoju [1 ]
Gao, Shuiying [1 ]
Li, Yafeng [1 ]
Cao, Rong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2007年 / 846卷 / 1-3期
关键词：
self-assembly; hydrogenbond; photoluminescence;
D O I：
10.1016/j.molstruc.2007.01.036
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A photoluminescent supramolecular compound [Cd(HbiC)(2)(H2O)]center dot(4,4'-bpy)center dot H2O, H(2)bic = 1-H-benzimidazole-5-carboxylic acid, has been synthesized and structurally characterized. With CH-pi stacking and hydrogen bond, the 4,4'-bipyridine is used as template to construct the neighboring layers into a three-dimensional supramolecular architecture. Solid-state emission spectrum Of Compound I shows luminescence with emission peak at 565 nm. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：123 / 127
页数：5
相关论文
共 37 条
[1]   TOPOLOGICAL REARRANGEMENT WITHIN A SINGLE-CRYSTAL FROM A HONEYCOMB [CD(CN)2]N3D NET TO A DIAMOND NET [J].
ABRAHAMS, BF ;
HARDIE, MJ ;
HOSKINS, BF ;
ROBSON, R ;
WILLIAMS, GA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10641-10643
[2]   Synthesis, structures, and magnetic properties of the copper(II), cobalt(II), and manganese(II) complexes with 9-acridinecarboxylate and 4-quinolinecarboxylate ligands [J].
Bu, XH ;
Tong, ML ;
Xie, YB ;
Li, JR ;
Chang, HC ;
Kitagawa, S ;
Ribas, J .
INORGANIC CHEMISTRY, 2005, 44 (26) :9837-9846
[3]   Aqueous chemistry of the vanadiumIII (VIII) and the VIII-dipicolinate systems and a comparison of the effect of three oxidation states of vanadium compounds on diabetic hyperglycemia in rats [J].
Buglyó, P ;
Crans, DC ;
Nagy, EM ;
Lindo, RL ;
Yang, LQ ;
Smee, JJ ;
Jin, WZ ;
Chi, LH ;
Godzala, ME ;
Willsky, GR .
INORGANIC CHEMISTRY, 2005, 44 (15) :5416-5427
[4]   NOVEL NETWORKS OF UNUSUALLY COORDINATED SILVER(I) CATIONS - THE WAFER-LIKE STRUCTURE OF [AG(PYZ)(2)][AG-2(PYZ)(5)](PF6)(3)CENTER-DOT-2G AND THE SIMPLE CUBIC FRAME OF [AG(PYZ)(3)](SBF6) [J].
CARLUCCI, L ;
CIANI, G ;
PROSERPIO, DM ;
SIRONI, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (17) :1895-1898
[5]   THERMODYNAMICS OF COMPLEXATION OF LANTHANIDES BY 3-FLUOROBENZOIC, 4-FLUOROBENZOIC, AND 3-NITROBENZOIC ACIDS [J].
CHOPPIN, GR ;
LAJUNEN, LHJ .
INORGANIC CHEMISTRY, 1986, 25 (19) :3512-3514
[6]   Luminescent Ln3+ nitrobenzoato complexes:: first examples of sensitization of green and red emission [J].
Dias, AD ;
Viswanathan, S .
CHEMICAL COMMUNICATIONS, 2004, (08) :1024-1025
[7]  
Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO
[8]  
2-3
[9]   EMERGENCE OF A CNH AND CYANO COMPLEX BASED ORGANOMETALLIC CHEMISTRY [J].
FEHLHAMMER, WP ;
FRITZ, M .
CHEMICAL REVIEWS, 1993, 93 (03) :1243-1280
[10]   A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].
FERLAY, S ;
MALLAH, T ;
OUAHES, R ;
VEILLET, P ;
VERDAGUER, M .
NATURE, 1995, 378 (6558) :701-703
1234