Novel fluorene-carzazole-based conjugated containing pyrazoline and benzothiazole segments for blue light-emitting materials

被引:9
作者
Chen, Hao [1 ]
Xu, Xing [1 ]
Yan, He Gang [1 ]
Cai, Xian Rong [1 ]
Li, Ying [1 ]
Jiang, Qing [1 ]
Xie, Ming Gui [1 ]
机构
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
关键词
fluorene-carbazole copolymers; pyrazoline; bezothiazole;
D O I
10.1016/j.cclet.2007.10.005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of novel fluorene-carbazole-based copolymers with pyrazoline and benzothiazole units were synthesized successfully through Suzuki coupling reactions. The molecular structures and thermal properties of these polymers were characterized by FT-IR, H-1 NMR, DSC and TGA. GPC results indicated that the weight-average molecular weight (M-w) and polydispersity of these polymers were in range (12,000-14,000) and (1.8-2.0), respectively. The two resulting polymers have high photoluminescence quantum efficiency implying that they may be promising candidates for polymer light-emitting diodes (PLEDs). (c) 2007 Ying Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码:1496 / 1500
页数:5
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