Thermodynamical study on pressure-induced compatibility in UCST polymer-containing mixtures

被引：0

作者：

Meng, YF

Jiang, SC ^{[1
]}

An, LJ

Jiang, BZ

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Yantai Normal Univ, Dept Chem, Yantai 264025, Peoples R China

来源：

SCIENCE IN CHINA SERIES B-CHEMISTRY | 2003年 / 46卷 / 04期

基金：

中国国家自然科学基金;

关键词：

UCST polymer mixture; pressure-induced compatibility; Sanchez-Lacombe fluid theory; polymer thermodynamics under pressure;

D O I：

10.1360/03yb0032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present calculations were performed on the basis of the Sanchez-Lacombe lattice fluid theory and the new combinatorial rules for block copolymer according to the experimental results on the pressure-induced compatibility in poly(ethylene oxide) (PEO) and poly(ethylene oxide-b-dimethylsiloxane) (P(EO-b-DMS)) mixtures with UCST behavior. The study on enthalpy, combinatorial entropy, vacancy entropy and Gibbs energy upon mixture shows that Sanchez-Lacombe fluid theory and the new combinatorial rules could describe the pressure-induced compatibility (PIC) of polymer mixtures with UCST behavior well.

引用

页码：352 / 360

页数：9

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