Arylation of unactivated arenes

被引:100
作者
Lei, Aiwen [1 ]
Liu, Wei [1 ]
Liu, Chao [1 ]
Chen, Mao [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
关键词
CATALYZED DIRECT ARYLATION; C-H ACTIVATION; NICKEL-PHOSPHINE COMPLEXES; CROSS-COUPLING REACTIONS; CARBON-HYDROGEN BONDS; AROMATIC-COMPOUNDS; GRIGNARD-REAGENTS; ORGANIC HALIDES; ARYL HALIDES; PALLADIUM;
D O I
10.1039/c0dt00486c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Transition metal-catalyzed and metal-free direct arylation of unactivated arenes is described. The transition metal-catalyzed direct arylation of unactivated arenes as a state-of-the-art method towards biaryl synthesis is highlighted in this Perspective.
引用
收藏
页码:10352 / 10361
页数:10
相关论文
共 67 条
[31]   OXIDATIVE COUPLING OF THIOPHENE CATALYZED BY PD(II) [J].
KOZHEVNIKOV, IV .
REACTION KINETICS AND CATALYSIS LETTERS, 1977, 6 (03) :401-408
[32]   Palladium-catalyzed benzene arylation: Incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design [J].
Lafrance, Marc ;
Fagnou, Keith .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16496-16497
[33]   Multiple C-H activations to construct biologically active molecules in a process completely free of organohalogen and organometallic components [J].
Li, Bi-He ;
Tian, Shi-Liang ;
Fang, Zhao ;
Shi, Zhang-Jie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (06) :1115-1118
[34]   Recent advances in direct arylation via palladium-catalyzed aromatic C-H activation [J].
Li, Bi-Jie ;
Yang, Shang-Dong ;
Shi, Zhang-Jie .
SYNLETT, 2008, (07) :949-957
[35]   Intermolecular cross-coupling of simple arenes via C-H activation by tuning concentrations of arenes and TFA [J].
Li, Ruoshi ;
Jiang, Li ;
Lu, Wenjun .
ORGANOMETALLICS, 2006, 25 (26) :5973-5975
[36]   Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C-H Arylation of Unactivated Benzene [J].
Liu, Wei ;
Cao, Hao ;
Zhang, Hua ;
Zhang, Heng ;
Chung, Kin Ho ;
He, Chuan ;
Wang, Haibo ;
Kwong, Fuk Yee ;
Lei, Aiwen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (47) :16737-16740
[37]   Iron-Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides [J].
Liu, Wei ;
Cao, Hao ;
Lei, Aiwen .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (11) :2004-2008
[38]   Atropisomerism, biphenyls and the Suzuki coupling: peptide antibiotics [J].
Lloyd-Williams, P ;
Giralt, E .
CHEMICAL SOCIETY REVIEWS, 2001, 30 (03) :145-157
[39]   Recent advances in aryl-aryl bond formation by direct arylation [J].
McGlacken, Gerard P. ;
Bateman, Lorraine M. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (08) :2447-2464
[40]   GENERAL, SELECTIVE, AND FACILE METHOD FOR KETONE SYNTHESIS FROM ACID-CHLORIDES AND ORGANOTIN COMPOUNDS CATALYZED BY PALLADIUM [J].
MILSTEIN, D ;
STILLE, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (11) :3636-3638