Flower-like CuO microspheres with enhanced catalytic performance for dimethyldichlorosilane synthesis

被引：42
|
作者：
Zhang, Zailei [1 ,2 ]
Che, Hongwei [1 ]
Wang, Yingli [1 ]
Gao, Jiajian [1 ]
She, Xilin [2 ]
Sun, Jin [2 ]
Zhong, Ziyi [3 ]
Su, Fabing [1 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[2] Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China
[3] ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore
来源：
RSC ADVANCES | 2012年 / 2卷 / 06期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
MECHANISM; METHYLCHLOROSILANES; FABRICATION; CU3SI; NANOSTRUCTURES; NANOWIRES; KINETICS; SILICON; REACTOR; PHASE;
D O I：
10.1039/c2ra00923d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Flower-like CuO microspheres synthesized by a facile hydrothermal method were found to be an effective catalyst for the Rochow reaction with a higher dimethyldichlorosilane selectivity and Si conversion because of the enhanced formation of an active CuxSi phase and mass transport.
引用
收藏
页码：2254 / 2256
页数：3
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