Flower-like CuO microspheres with enhanced catalytic performance for dimethyldichlorosilane synthesis

被引:42
|
作者
Zhang, Zailei [1 ,2 ]
Che, Hongwei [1 ]
Wang, Yingli [1 ]
Gao, Jiajian [1 ]
She, Xilin [2 ]
Sun, Jin [2 ]
Zhong, Ziyi [3 ]
Su, Fabing [1 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[2] Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China
[3] ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
MECHANISM; METHYLCHLOROSILANES; FABRICATION; CU3SI; NANOSTRUCTURES; NANOWIRES; KINETICS; SILICON; REACTOR; PHASE;
D O I
10.1039/c2ra00923d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flower-like CuO microspheres synthesized by a facile hydrothermal method were found to be an effective catalyst for the Rochow reaction with a higher dimethyldichlorosilane selectivity and Si conversion because of the enhanced formation of an active CuxSi phase and mass transport.
引用
收藏
页码:2254 / 2256
页数:3
相关论文
共 50 条
  • [21] Synthesis, Characterization and Photocatalytic Activity for Flower-Like Microspheres of ZnO Nanosheets
    Wang Zhi-Fang
    Li Mi
    Zhang Hong-Xia
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (04) : 715 - 720
  • [22] Synthesis and enhanced gas sensing properties of flower-like ZnO nanorods decorated with discrete CuO nanoparticles
    Zhang, Bowen
    Fu, Wuyou
    Li, Huayang
    Fu, Xinglin
    Wang, Ying
    Bala, Hari
    Wang, Xiaodong
    Sun, Guang
    Cao, Jianliang
    Zhang, Zhanying
    MATERIALS LETTERS, 2016, 176 : 13 - 16
  • [23] Synthesis and tribological properties of flower-like MoS2 microspheres
    Tang, Guogang
    Zhang, Jing
    Liu, Changchao
    Zhang, Du
    Wang, Yuqi
    Tang, Hua
    Li, Changsheng
    CERAMICS INTERNATIONAL, 2014, 40 (08) : 11575 - 11580
  • [24] Facile synthesis of flower-like nickel nanocrystals and properties
    Zhang, DongEn
    Yang, Wen
    Wang, MingYan
    Zhang, XiaoBo
    Li, ShanZhong
    Han, GuiQuan
    Ying, AiLing
    Tong, ZhiWei
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2011, 72 (12) : 1397 - 1399
  • [25] Facile synthesis of 3D flower-like Ni microspheres with enhanced microwave absorption properties
    Liu, Dawei
    Du, Yunchen
    Li, Zhennan
    Wang, Yahui
    Xu, Ping
    Zhao, Honghong
    Wang, Fengyuan
    Li, Chaolong
    Han, Xijiang
    JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (36) : 9615 - 9623
  • [26] Low temperature pH dependent synthesis of flower-like ZnO nanostructures with enhanced photocatalytic activity
    Vaishampayan, Mukta V.
    Mulla, Imtiaz S.
    Joshi, Satyawati S.
    MATERIALS RESEARCH BULLETIN, 2011, 46 (05) : 771 - 778
  • [27] Synthesis of ionic liquid-modified BiPO4 microspheres with hierarchical flower-like architectures and enhanced photocatalytic activity
    Lv, Hua
    Guang, Jing
    Liu, Yumin
    Tang, Haibo
    Zhang, Peng
    Lu, Yan
    Wang, Jianji
    RSC ADVANCES, 2015, 5 (122): : 100625 - 100632
  • [28] Synthesis of flower-like cuo hierarchical nanostructures as an electrochemical platform for glucose sensing
    Medeiros, Natalia Goedtel
    Ribas, Vanessa Cezar
    Lavayen, Vladimir
    Da Silva, Jacqueline Arguello
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2016, 20 (09) : 2419 - 2426
  • [29] Electrochemical hydrogen storage performance of hierarchical Co metal flower-like microspheres
    Lee, Dong Heon
    Kang, Myunggoo
    Paek, Seung-Min
    Jung, Hyun
    ELECTROCHIMICA ACTA, 2016, 217 : 132 - 138
  • [30] A simple hydrothermal synthesis of flower-like ZnO microspheres and their improved photocatalytic activity
    Wang, Yuxin
    Yang, Yiqiong
    Xi, Limin
    Zhang, Xiaodong
    Jia, Minghan
    Xu, Hongming
    Wu, Hangui
    MATERIALS LETTERS, 2016, 180 : 55 - 58