A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules:: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]•34H2O

被引：5

作者：

Izarova, NV

Sokolov, MN

Dolgushin, FM

Antipin, MY

Fenske, D

Fedin, VP

机构：

[1] Russian Acad Sci, Nikolayev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[3] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

COMPTES RENDUS CHIMIE | 2005年 / 8卷 / 11-12期

基金：

俄罗斯基础研究基金会;

关键词：

polyoxometalate; molybdenum; gadolinium; coordination polymer; crystal structure;

D O I：

10.1016/j.crci.2005.02.025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the ammonium salt of keplerate, [{(Mo-VI)(Mo5O21)-O-VI(H2O)(6)}(12){(Mo2O4CHCOO)-O-V-C-3)}(30)](42-) with Gd(NO3)(3) leads to complex transformations with [{Gd(H2O)(5)}(4){Mo-36(NO)(4)O-108(H2O)(16)}]-34 H2O (1) as final product. According to X-ray structural data it contains anions [Mo-36(NO)(4)O-108(H2O)(16)](12-), cross-linked into a neutral 2D-framework by Gd3+ ions.

引用

页码：1922 / 1926

页数：5

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[4]

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