The application of the formyl C-H--O hydrogen bond postulate to the understanding of enantioselective reactions involving chiral boron Lewis acids and aldehydes

被引：97
作者：
Corey, EJ
Rohde, JJ
机构：
[1] Department of Chemistry, Harvard University, Cambridge
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 01期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(96)02249-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A number of noteworthy enantioselective reactions involving a variety of chiral boron Lewis acids and aldehydes can be rationalized in terms of the occurrence of formyl CH-O hydrogen bonds in the transition states and the additional three-dimensional organization which they provide. Copyright (C) 1996 Elsevier Science Ltd
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页码：37 / 40
页数：4
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