Preparation of cross-linked poly(vinyl alcohol) films from copolymers with benzoxaborole and carboxylic acid groups, and their degradability in an oxidizing environment

被引:23
作者
Hakuto, Nao [1 ]
Saito, Katsuya [1 ]
Kirihara, Masayuki [1 ]
Kotsuchibashi, Yohei [1 ]
机构
[1] Shizuoka Inst Sci & Technol, Dept Mat & Life Sci, 2200-2 Toyosawa, Shizuoka 4378555, Japan
关键词
POLYVINYL-ALCOHOL; DEGRADATION; HYDROGELS; TEMPERATURE; POLYMERS;
D O I
10.1039/d0py00153h
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Functionalized PVA films were prepared from copolymers with benzoxaborole and carboxyl groups. The hydroxy groups of PVA were cross-linked by two kinds of covalent bonds. The water-insoluble functionalized PVA films were degraded by the oxidizing nature of NaClO center dot 5H(2)O aqueous solution within 25 hours at 25 degrees C.
引用
收藏
页码:2469 / 2474
页数:6
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共 30 条
[1]   Microplastics in the marine environment: Current trends in environmental pollution and mechanisms of toxicological profile [J].
Alimba, Chibuisi Gideon ;
Faggio, Caterina .
ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY, 2019, 68 :61-74
[2]   Microplastics and Nanoplastics in Aquatic Environments: Aggregation, Deposition, and Enhanced Contaminant Transport [J].
Alimi, Olubukola S. ;
Budarz, Jeffrey Farner ;
Hernandez, Laura M. ;
Tufenkji, Nathalie .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2018, 52 (04) :1704-1724
[3]   Crosslinked poly(vinyl alcohol) membranes [J].
Bolto, Brian ;
Tran, Thuy ;
Hoang, Manh ;
Xie, Zongli .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (09) :969-981
[4]   Bioinspired Self-Healing Hydrogel Based on Benzoxaborole-Catechol Dynamic Covalent Chemistry for 3D Cell Encapsulation [J].
Chen, Yangjun ;
Diaz-Dussan, Diana ;
Wu, Di ;
Wang, Wenda ;
Peng, Yi-Yang ;
Asha, Anika Benozir ;
Hall, Dennis G. ;
Ishihara, Kazuhiko ;
Narain, Ravin .
ACS MACRO LETTERS, 2018, 7 (08) :904-908
[5]   Biodegradation of poly (vinyl alcohol) based materials [J].
Chiellini, E ;
Corti, A ;
D'Antone, S ;
Solaro, R .
PROGRESS IN POLYMER SCIENCE, 2003, 28 (06) :963-1014
[6]   Thermoresponsive Polymers and Inverse Opal Hydrogels for the Detection of Diols [J].
Couturier, Jean-Philippe ;
Wischerhoff, Erik ;
Bernin, Robert ;
Hettrich, Cornelia ;
Koetz, Joachim ;
Sutterlin, Martin ;
Tiersch, Brigitte ;
Laschewsky, Andre .
LANGMUIR, 2016, 32 (17) :4333-4345
[7]   Review of the oral toxicity of polyvinyl alcohol (PVA) [J].
DeMerlis, CC ;
Schoneker, DR .
FOOD AND CHEMICAL TOXICOLOGY, 2003, 41 (03) :319-326
[8]   Effective and Specific Gene Silencing of Epidermal Growth Factor Receptors Mediated by Conjugated Oxaborole and Galactose-Based Polymers [J].
Diaz-Dussan, Diana ;
Nakagawa, Yasuhiro ;
Peng, Yi-Yang ;
Sanchez, Leslie V. C. ;
Ebara, Mitsuhiro ;
Kumar, Piyush ;
Narain, Ravin .
ACS MACRO LETTERS, 2017, 6 (07) :768-774
[9]   An improved class of sugar-binding boronic acids, soluble and capable of complexing glycosides in neutral water [J].
Dowlut, M ;
Hall, DG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (13) :4226-4227
[10]   Plastics of the Future? The Impact of Biodegradable Polymers on the Environment and on Society [J].
Haider, Tobias P. ;
Voelker, Carolin ;
Kramm, Johanna ;
Landfester, Katharina ;
Wurm, Frederik R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (01) :50-62