Microwave-Assisted Debromination of α-Bromoketones with Triarylstibanes in Water

被引：0
|
作者：
Murata, Yuki [1 ]
Sugawara, Yoshiyuki [2 ]
Matsumura, Mio [1 ]
Kakusawa, Naoki [2 ]
Yasuike, Shuji [1 ]
机构：
[1] Aichi Gakuin Univ, Sch Pharmaceut Sci, Chikusa Ku, 1-100 Kusumoto Cho, Nagoya, Aichi 4648650, Japan
[2] Hokuriku Univ, Fac Pharmaceut Sci, Ho 3 Kanagawa Machi, Kanazawa, Ishikawa 9201181, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2017年 / 65卷 / 11期
关键词：
microwave; debromination; alpha-bromoketone; triarylstibane; water; HALO CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; REDUCTIVE DEHALOGENATION; ORGANOANTIMONY COMPOUNDS; TRANSMETALLATING AGENT; TERTIARY STIBINE; KETONES; ALDEHYDES; HALIDES; LIGAND;
D O I：
10.1248/cpb.c17-00533
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Several alpha-bromoarylketones were reacted with triarylstibanes under microwave irradiation in water to obtain the corresponding debrominated ketones. Under similar reaction conditions, 1,2-elimination of vicdibromides in water afforded the corresponding E-olefins. This reaction is the first example of organoantimony compounds utilized for organic transformation in water.
引用
收藏
页码：1081 / 1084
页数：4
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