Microwave-Assisted Debromination of α-Bromoketones with Triarylstibanes in Water

被引：0
|
作者：
Murata, Yuki [1 ]
Sugawara, Yoshiyuki [2 ]
Matsumura, Mio [1 ]
Kakusawa, Naoki [2 ]
Yasuike, Shuji [1 ]
机构：
[1] Aichi Gakuin Univ, Sch Pharmaceut Sci, Chikusa Ku, 1-100 Kusumoto Cho, Nagoya, Aichi 4648650, Japan
[2] Hokuriku Univ, Fac Pharmaceut Sci, Ho 3 Kanagawa Machi, Kanazawa, Ishikawa 9201181, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2017年 / 65卷 / 11期
关键词：
microwave; debromination; alpha-bromoketone; triarylstibane; water; HALO CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; REDUCTIVE DEHALOGENATION; ORGANOANTIMONY COMPOUNDS; TRANSMETALLATING AGENT; TERTIARY STIBINE; KETONES; ALDEHYDES; HALIDES; LIGAND;
D O I：
10.1248/cpb.c17-00533
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Several alpha-bromoarylketones were reacted with triarylstibanes under microwave irradiation in water to obtain the corresponding debrominated ketones. Under similar reaction conditions, 1,2-elimination of vicdibromides in water afforded the corresponding E-olefins. This reaction is the first example of organoantimony compounds utilized for organic transformation in water.
引用
收藏
页码：1081 / 1084
页数：4
相关论文
共 50 条
  • [31] Microwave-assisted hydrogenation of pyridines
    Piras, Leonarda
    Genesio, Eva
    Ghiron, Chiara
    Taddei, Maurizio
    SYNLETT, 2008, (08) : 1125 - 1128
  • [32] Microwave-assisted chemical reactions
    Man, Ah Keow
    Shahidan, Radiman
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2007, 44 (4-6): : 651 - 657
  • [33] A microwave-assisted microassay for lipases
    Jain, P
    Jain, S
    Gupta, MN
    ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2005, 381 (07) : 1480 - 1482
  • [34] Microwave-assisted synthesis of metalloporphyrins
    Singh, R
    Geetanjali
    ASIAN JOURNAL OF CHEMISTRY, 2005, 17 (01) : 612 - 614
  • [35] Microwave-Assisted Biocatalytic Polymerizations
    Mahapatro, Anil
    Negron, Taina D. Matos
    GREEN POLYMER CHEMISTRY: BIOCATALYSIS AND MATERIALS II, 2013, 1144 : 69 - 80
  • [36] Microwave-assisted Chemical Transformations
    Takkellapati, Sudhakar R.
    CURRENT ORGANIC CHEMISTRY, 2013, 17 (20) : 2305 - 2322
  • [37] Microwave-assisted olefin metathesis
    Coquerel, Yoann
    Rodriguez, Jean
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (07) : 1125 - 1132
  • [38] Evaluating the potential nonthermal microwave effects of microwave-assisted proteolytic reactions
    Reddy, P. Muralidhar
    Huang, Yu-Shan
    Chen, Cheng-Tung
    Chang, Po-Chi
    Ho, Yen-Peng
    JOURNAL OF PROTEOMICS, 2013, 80 : 160 - 170
  • [39] A microwave-assisted microassay for lipases
    Parul Jain
    Sulakshana Jain
    M. N. Gupta
    Analytical and Bioanalytical Chemistry, 2005, 381 : 1480 - 1482
  • [40] Microwave-Assisted Synthesis of α-Diazoesters
    Yi, Xiangyan
    Zhang, Zhipeng
    Huang, He
    Baell, Jonathan B.
    Yu, Yang
    Huang, Fei
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (02) : 544 - 549
12345