Polymer-based dielectrics with high permittivity for electric energy storage: A review

被引：232

作者：

Zha, Jun-Wei ^{[1
,2
]}

Zheng, Ming-Sheng ^{[1
]}

Fan, Ben-Hui ^{[3
]}

Dang, Zhi-Min ^{[4
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China

[2] Univ Sci & Technol Beijing, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China

[3] Cerema Ouest DLAn, 23 Ave Amiral Chauvin,CS 2006949136, Les Ponts de Ce, France

[4] Tsinghua Univ, Dept Elect Engn, State Key Lab Power Syst, Beijing 100084, Peoples R China

来源：

NANO ENERGY | 2021年 / 89卷

基金：

中国国家自然科学基金;

关键词：

Dielectric polymers; Multi-structures; High permittivity; Processing; FERROELECTRIC PHASE-TRANSITION; POLY(VINYLIDENE FLUORIDE) FILM; BARIUM-TITANATE NANOPARTICLES; VINYLIDENE FLUORIDE; BREAKDOWN STRENGTH; THIN-FILMS; CARBON NANOTUBE; HYPERELECTRONIC POLARIZATION; ELECTROMECHANICAL PROPERTIES; ELECTROCHEMICAL PROPERTIES;

D O I：

10.1016/j.nanoen.2021.106438

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polymer-based dielectrics (PDs) with improved permittivity (k) have considerable applications including ca-pacitors, actuator devices and electrical power systems due to their flexibility, easy processability and low weight, etc. However, the permittivity values of commonly used polymers (usually k < 3) fails to meet the re-quirements of the advanced electrical components. Enormous research, including numerical and experimental works has shown that developing polymer based multi-phase materials represents the most promising avenue. This review will clarify the concepts and relationships based on the polarization mechanisms and meanwhile some key factors of improving permittivity will also be discussed including polymer chains/segments, morphology, the interface of nanofillers-matrix, processing, and multilayer structures. Combining with the recent specific advances in PDs, the latest developments in this field will be summarized which are the introduction of polar functional groups/copolymer segments, the application of core-shell nanofillers and the technology of multi-layers structures. We hope to help readers to comprehensively understand the fabrication of PDs from the selection of molecular units to the design of composites in order to provide guidance on achieving polymer based materials with high permittivity.

引用

页数：20

共 258 条

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