Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials

被引：30

作者：

Murugavel, R ^{[1
]}

Sathiyendiran, M ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

CHEMISTRY LETTERS | 2001年 / 01期

关键词：

D O I：

10.1246/cl.2001.84

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)(4)] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene. imidazole and water to finally yield the respective ceramic materials Mn(PO3)(2) or Cu(PO3)(2).

引用

页码：84 / 85

页数：2

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