Ranking environmental degradation trends of plastic marine debris based on physical properties and molecular structure

被引:345
作者
Min, Kyungjun [1 ]
Cuiffi, Joseph D. [2 ]
Mathers, Robert T. [1 ]
机构
[1] Penn State Univ, Dept Chem, New Kensington, PA 15068 USA
[2] Penn State Univ, Dept Elect Mech Engn Technol, New Kensington, PA 15068 USA
关键词
ALIPHATIC POLYESTERS; POLYMERS; WATER; PHOTODEGRADATION; BIODEGRADATION; MICROPLASTICS; POLYETHYLENE; POLYLACTIDE; HYDROLYSIS; CHEMISTRY;
D O I
10.1038/s41467-020-14538-z
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
As plastic marine debris continues to accumulate in the oceans, many important questions surround this global dilemma. In particular, how many descriptors would be necessary to model the degradation behavior of ocean plastics or understand if degradation is possible? Here, we report a data-driven approach to elucidate degradation trends of plastic debris by linking abiotic and biotic degradation behavior in seawater with physical properties and molecular structures. The results reveal a hierarchy of predictors to quantify surface erosion as well as combinations of features, like glass transition temperature and hydrophobicity, to classify ocean plastics into fast, medium, and slow degradation categories. Furthermore, to account for weathering and environmental factors, two equations model the influence of seawater temperature and mechanical forces.
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页数:11
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