Isolation of a uranyl[UO2]+ species:: Crystallographic comparison of the dioxouranium(V) and (VI) compounds [UO2(OPPh3)4] (OTf)n (n=1, 2)

被引：79
作者：
Berthet, JC [1 ]
Nierlich, M [1 ]
Ephritikhine, M [1 ]
机构：
[1] CEA Saclay, CNRS, URA 331, DRECAM,DSM,Serv Chim Mol, F-91191 Gif Sur Yvette, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 17期
关键词：
actinides; ion pairs; O ligands; structure elucidation; uranium;
D O I：
10.1002/anie.200250506
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Variations in the structural parameters of the analogous [UO2]2+ and [UO2]+ compounds, [UO2(OPPh3)4](OTf)n (n = 1, 2; picture shows the cation of the n = 1 complex), allow a direct comparison of the observed data with that obtained from EXAFS studies in solution, and from theoretical studies.
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收藏
页码：1952 / 1954
页数：3
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