Nickel-based nanocoatings on 3D Ni foam for zero-gap alkaline water electrolysis

被引：14

作者：

Zachenska, Jana ^{[1
]}

Abel, Maros ^{[1
]}

Micusik, Matej ^{[2
]}

Jorik, Vladimir ^{[1
]}

Zemanova, Matilda ^{[1
]}

机构：

[1] Slovak Univ Technol Bratislava, Inst Inorgan Chem Technol & Mat, Radlinskeho 9, Bratislava 81237, Slovakia

[2] Slovak Acad Sci, Polymer Inst, Dubravska Cesta 9, Bratislava 84541, Slovakia

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2020年 / 50卷 / 09期

关键词：

Electrodeposition of 3D nickel foam; Ni and Ni-W coatings; Alkaline water electrolysis; Electrocatalysis; Hydrogen evolution reaction; HYDROGEN EVOLUTION REACTION; ELECTROCATALYSTS; CATALYSTS; DESIGN; ALLOYS; PARAMETERS; MEMBRANE; ECONOMY;

D O I：

10.1007/s10800-020-01448-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The active surface of the 3D nickel foam electrodes was prepared by electrodeposition. Nickel-based metallic nanocoatings were deposited on pure nickel foam. Optimum parameters of the electrodeposition were found using the central composite rotatable design optimisation method. Pure nickel foam, electrodeposited nickel, and Ni-W coatings on the foam were tested for the load and stability measurements by zero-gap alkaline water electrolysis. It was found that Ni-W surface layer was superior to the nickel coating. This can be explained by a higher amount of active sites due to W content. [GRAPHICS] .

引用

页码：959 / 971

页数：13

共 33 条

[1] The hydrogen economy in the 21st century: a sustainable development scenario
Barreto, L
Makihira, A
Riahi, K
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (03) : 267 - 284
[2] Uncoupled non-linear equations method for determining kinetic parameters in case of hydrogen evolution reaction following Volmer-Heyrovsky-Tafel mechanism and Volmer-Heyrovsky mechanism
Bhardwaj, Mukesh
Balasubramaniam, R.
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (09) : 2178 - 2188
[3] Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting
Chaudhari, Nitin K.
Jin, Haneul
Kim, Byeongyoon
Lee, Kwangyeol
[J]. NANOSCALE, 2017, 9 (34) : 12231 - 12247
[4] Corrosion of nanocrystalline Ni-W alloys in alkaline and acidic 3.5 wt.% NaCl solutions
Chianpairot, Amnuaysak
Lothongkum, Gobboon
Schuh, Christopher A.
Boonyongmaneerat, Yuttanant
[J]. CORROSION SCIENCE, 2011, 53 (03) : 1066 - 1071
[5] Stand-alone PEM water electrolysis system for fail safe operation with a renewable energy source
Clarke, R. E.
Giddey, S.
Badwal, S. P. S.
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (03) : 928 - 935
[6] Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
Diaz, Liliana A.
Hnat, Jaromir
Heredia, Nayra
Bruno, Mariano M.
Viva, Federico A.
Paidar, Martin
Corti, Horacio R.
Bouzek, Karel
Abuin, Graciela C.
[J]. JOURNAL OF POWER SOURCES, 2016, 312 : 128 - 136
[7] New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
Durst, J.
Siebel, A.
Simon, C.
Hasche, F.
Herranz, J.
Gasteiger, H. A.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (07) : 2255 - 2260
[8] Synthesis and characterization of nickel tungsten alloys by electrodeposition
Eliaz, N
Sridhar, TM
Gileadi, E
[J]. ELECTROCHIMICA ACTA, 2005, 50 (14) : 2893 - 2904
[9] Design of experiment approach applied to reducing and oxidizing tolerance of anode supported solid oxide fuel cell. Part I: Microstructure optimization
Faes, Antonin
Fuerbringer, Jean-Marie
Mohamedi, Driss
Hessler-Wyser, Aiecha
Caboche, Gilles
Van Herle, Jan
[J]. JOURNAL OF POWER SOURCES, 2011, 196 (17) : 7058 - 7069
[10] 3D nanostructured NiMo catalyst electrodeposited on 316L stainless steel for hydrogen generation in industrial applications
Gomez, Melisa J.
Diaz, Liliana A.
Franceschini, Esteban A.
Lacconi, Gabriela, I
Abuin, Graciela C.
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2019, 49 (12) : 1227 - 1238

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