Isobaric Vapor-Liquid Equilibrium for Methanol plus Methyl Acetate+1-Octyl-3-methylimidazolium Hexafluorophosphate at 101.3 kPa

被引：38

作者：

Cai, Jialin ^{[1
]}

Cui, Xianbao ^{[1
]}

Zhang, Ying ^{[1
]}

Li, Rui ^{[1
]}

Feng, Tianyang ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, State Key Lab Chem Engn, Tianjin 300072, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 06期

关键词：

IONIC LIQUIDS; EXTRACTIVE DISTILLATION; 1-ETHYL-3-METHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE; BUTYL ACETATE; SYSTEMS; PREDICTION; SEPARATION; WATER;

D O I：

10.1021/je2000588

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor-liquid equilibrium (VLE) data for methanol + methyl acetate + 1-octyl-3-methylimidazolium hexafluorphosphate ([OMIM][PF6]) at 101.3 kPa were measured. The experimental VLE data were correlated by the nonrandom two-liquid (NRTL) activity coefficient model, and the binary parameters were obtained. The results show that the ionic liquid [OMIM][PF6] produces a notable salting-out effect, which enhances the relative volatility of methanol to methyl acetate. The effect of [OMIM][PF6] on methanol + methyl acetate system was compared with that of o-xylene.

引用

页码：2884 / 2888

页数：5

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