Acceptor directionality of sterically unhindered C-H center dot center dot center dot O=C hydrogen bonds donated by acidic C-H groups

被引:43
|
作者
Steiner, T [1 ]
Kanters, JA [1 ]
Kroon, J [1 ]
机构
[1] UNIV UTRECHT,DEPT CRYSTAL & STRUCT CHEM,BIJVOET CTR BIOMOL RES,3584 CH UTRECHT,NETHERLANDS
关键词
D O I
10.1039/cc9960001277
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystal correlation study of acidic and sterically unhindered C-H groups (chloroform, dichloromethane and terminal alkynes) forming short contacts with carbonyl accepters, reveals a soft but significant preference for the conventional carbonyl lone-pair direction.
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页码:1277 / 1278
页数:2
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