Condensation products of 1-aryl-4-hydrazinocarbonyl-2-pyrrolidinones with diketones

被引:3
|
作者
Mickevicius, V. [1 ]
Vaickelioniene, R. [1 ]
机构
[1] Kaunas Univ Technol, LT-50254 Kaunas, Lithuania
关键词
1-aryl-4-hydrazinocarbonyl-2-pyrrolidinones; N-(2,5-dimethylpyrrol-1-yl)-1-aryl-5-oxo-3-pyrrolidinecarboxamides; 1-aryl-4-(3,5-dimethyl-1-pyrazolylcarbonyl)-2-pyrrolidinones; 2,5-hexanedione; 2,4-pentanedione; condensation;
D O I
10.1007/s10593-008-0031-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of 1-aryl-4-hydrazinocarbonyl-2-pyrrolidinones with 2,4-pentanedione and 2,5-hexanedione have been studied. It was found that heating the hydrazinocarbonyl compounds with 2,4-pentanedione gave 3,5-dimethylpyrazole compounds and with 2,5-hexanedione gave 1-substituted 2,5-dimethylpyrroles.
引用
收藏
页码:170 / 172
页数:3
相关论文
共 50 条
  • [21] Synthesis of 4-(5-aryl-1 3,4-oxadiazol-2-yl)phenyl-hydrazine derivatives from 3-(4-hydrazinocarbonyl-phenyl)sydnones
    Chang, Hung-Te
    Chiang, Kuo-Chen
    Wong, Fung Fuh
    Huang, Chun-Sheng
    Liao, Yang-Ming
    Kuo, Wen-Fa
    Won, Shaw-Bing
    Yeh, Mou-Yung
    HETEROATOM CHEMISTRY, 2007, 18 (04) : 438 - 442
  • [22] SYNTHESIS AND CERTAIN REACTIONS OF 1-ARYL-4-(2-QUINOLYL)-1,3-BUTANEDIONES, A NEW CLASS OF BETA-DIKETONES
    WOLFE, JF
    MURRAY, TP
    JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (02): : 354 - &
  • [24] Reaction of singlet oxygen with enolic tautomers of 1-aryl-2-methyl 1,3-diketones
    Yoshioka, M
    Hashimoto, K
    Fukuhara, T
    Hasegawa, T
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (02): : 283 - 288
  • [25] Aryl pyrrolidinones via radical 1,4-aryl migration and 5-endo-trig cyclisation of N-(2-bromoallyl)arylcarboxamides
    Palframan, Matthew J.
    Tchabanenko, Kirill
    Robertson, Jeremy
    TETRAHEDRON LETTERS, 2006, 47 (47) : 8423 - 8425
  • [26] Diversity Oriented Synthesis of Polycyclic Heterocycles through the Condensation of 2-Amino[1,2,4]triazolo[1,5-a]pyrimidines with 1,3-Diketones
    Pyatakov, Dmitry A.
    Sokolov, Andrey N.
    Astakhov, Alexander V.
    Chemenko, Andrey Yu.
    Fakhrutdinov, Artem N.
    Rybakov, Victor B.
    Chemyshev, Vladimir V.
    Chernyshev, Victor M.
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (21): : 10694 - 10709
  • [27] SYNTHESES WITH NITRILES .70. CONDENSATION PRODUCTS OF DIMERIC MALONONITRILE DERIVATIVES WITH 2,4-DIKETONES AND THEIR APPLICATION FOR THE SYNTHESIS OF SUBSTITUTED 1,6-NAPHTYRIDINES
    KOITZ, G
    THIERRICHTER, B
    JUNEK, H
    HETEROCYCLES, 1983, 20 (12) : 2405 - 2409
  • [28] A CONFIRMATION OF THE STRUCTURE OF 2-6-DIMETHYL-4-PYRIMIDYL-METHYL-LITHIUM AND SOME OBSERVATIONS ON THE CONDENSATION OF 1-3-DIKETONES WITH ACETAMIDINE
    ROBERTS, JC
    JOURNAL OF THE CHEMICAL SOCIETY, 1952, (AUG): : 3065 - 3068
  • [29] Studies on the reduction of the nitro group in 3-aryl-2-methylene-4-nitro-alkanoates afforded by the Baylis-Hillman adducts:: synthesis of 4-aryl-3-methylene-2-pyrrolidinones and 3-(1-alkoxycarbonyl-vinyl)-1H-indole-2-carboxylates
    Singh, Vijay
    Kanojiya, Sanjeev
    Batra, Sanjay
    TETRAHEDRON, 2006, 62 (43) : 10100 - 10110
  • [30] Structure of the products of condensation of hydroxylamine with trifluoromethyl-β-diketones:: assignments of the diastereotopic protons of the 4-methylene group in 5-hydroxy-5-trifluoromethyl-Δ2-isoxazolines
    Sanz, D
    Claramunt, RM
    Singh, SP
    Kumar, V
    Aggarwal, R
    Elguero, J
    Alkorta, I
    MAGNETIC RESONANCE IN CHEMISTRY, 2005, 43 (12) : 1040 - 1043