Serine-based helical polyacetylenes. Effect of hydroxyl group on the secondary structure

被引：45

作者：

Sanda, F ^{[1
]}

Araki, H ^{[1
]}

Masuda, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

MACROMOLECULES | 2005年 / 38卷 / 25期

关键词：

D O I：

10.1021/ma051869a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of hydroxyl group on the secondary structure of serine-based helical polyacetylenes was investigated. The structures of the polymers were examined by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. It was found that derivating from the two conformers, the distance between the pendent groups becomes longer. It was confirmed that the hydroxyl groups greatly affect the secondary structures of the polymers, which was supported by liquid-state IR and molecular modeling studies.

引用

页码：10605 / 10608

页数：4

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