Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones

被引：79

作者：

Zeng, Fanlong ^{[1
]}

Yu, Zhengkun ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 13期

关键词：

D O I：

10.1021/om8002043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rare ruthenium(II) complexes bearing a pyridyl-based pyrazolyl-imidazolyl ligand were synthesized and exhibited exceptionally high catalytic activity in the transfer hydrogenation of ketones in 2-propanol at 82 degrees C or room temperature, reaching 100% conversion of the substrates and final TOFs up to 7.2 x 10(5) h(-1) with 0.05 mol % catalyst at 82 degrees C and 55 800 h(-1) with 0.1 mol % catalyst at room temperature.

引用

页码：2898 / 2901

页数：4

共 52 条

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