Preparation of functionally gradient fluorocarbon polymer films by plasma polymerization of NF3 and propylene

被引：0

作者：

Tasaka, A

Komura, A

Uchimoto, Y

Inaba, M

Ogumi, Z

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

[2] DOSHISHA UNIV,FAC ENGN,DEPT MOLEC SCI & TECHNOL,TANABE,KYOTO 61003,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1996年 / 34卷 / 02期

关键词：

plasma polymerization; fluorocarbon film; functionally gradient material; propylene; nitrogen trifluoride;

D O I：

10.1002/(SICI)1099-0518(19960130)34:2<193::AID-POLA5>3.3.CO;2-T

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Fluorocarbon polymer films were prepared by plasma polymerization using nitrogen trifluoride (NF3) and propylene as starting materials. To improve their adhesiveness to substrates, a novel functionally gradient film in which the content of fluorine decreased continuously from the surface to the interior was prepared by changing source gas composition during deposition. This film had a smooth and pinhole-free surface, and had a high contact angle (110 degrees) for water drop. In addition, it showed good adhesion to a glass substrate. (C) 1996 John Wiley & Sons, Inc.

引用

页码：193 / 198

页数：6

共 21 条

[1]

ADAMSON AW, 1990, PHYSICAL CHEM SURFAC, P397

[2]

BIEDERMAN H, 1992, PLASMA POLYM PROCESS, pCH4

[3] MECHANISMS OF POLYMERIZATION IN DISCHARGES OF FLUOROCARBONS [J].