N-Heterocyclic carbene catalysed aerobic oxidation of aromatic aldehydes to aryl esters using boronic acids

被引：41

作者：

Arde, Panjab ^{[1
]}

Ramanjaneyulu, B. T. ^{[1
]}

Reddy, Virsinha ^{[1
]}

Saxena, Apurv ^{[1
]}

Anand, R. Vijaya ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res IISER Mohali, Sect 81, Manuali 140306, Punjab, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 04期

关键词：

CARBOXYLIC-ACIDS; ALPHA; BETA-UNSATURATED ALDEHYDES; ESTERIFICATION; ALCOHOLS; CARBONYLATION; CO2;

D O I：

10.1039/c1ob06566a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.

引用

页码：848 / 851

页数：4

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