Ionic Liquids-Based Extraction: A Promising Strategy for the Advanced Nuclear Fuel Cycle

被引：767

作者：

Sun, Xiaoqi ^{[1
,4
]}

Luo, Huimin ^{[2
]}

Dai, Sheng ^{[1
,3
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Oak Ridge Natl Lab, Energy & Transportat Sci Div, Oak Ridge, TN 37831 USA

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37916 USA

[4] Chinese Acad Sci, Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

CHEMICAL REVIEWS | 2012年 / 112卷 / 04期

关键词：

SUPERCRITICAL CARBON-DIOXIDE; SURFACE-TENSION MEASUREMENTS; FUNCTIONALIZED SIDE-CHAINS; INDUCED REDOX REACTIONS; DIFFERENT HEAD GROUPS; NITRIC-ACID MEDIUM; ROOM-TEMPERATURE; MOLECULAR-DYNAMICS; 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE; ELECTROCHEMICAL-BEHAVIOR;

D O I：

10.1021/cr200193x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to demonstrate that ionic liquids-based extraction had emerged as a potential strategy for the advanced nuclear fuel cycle (NFC). The advanced NFC maximized fuel resource utilization, reduced the volume and toxicity of nuclear waste, facilitated handling and transportation, and saved on geological repository costs. Room-temperature ionic liquids (ILs), a novel type of solvent, showed significant potential as a separation technology for the advanced NFC. Room-temperature ionic liquids were defined as room-temperature molten salts, which were composed of cations and anions, and their melting points were below 100 °C. The ILs gained significance for their preparation, purification, physicochemical properties, solvation environment, partitioning behavior, and extraction mechanism, along with strategies for improvement and a forecast of IL-based extraction from the viewpoint of promising technologies for the advanced NFC.

引用

页码：2100 / 2128

页数：29

共 338 条

[1] Application of ionic liquids to the electrodeposition of metals [J].

Abbott, Andrew P. ;

McKenzie, Katy J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (37) :4265-4279

[2] Recent advances in nuclear power: A review [J].

Abu-Khader, Mazen M. .

PROGRESS IN NUCLEAR ENERGY, 2009, 51 (02) :225-235

[3] Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids [J].

Ahrens, Sebastian ;

Peritz, Anke ;

Strassner, Thomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) :7908-7910

[4] Sulfonic Acid Functionalized Ionic Liquid in Combinatorial Approach, a Recyclable and Water Tolerant-Acidic Catalyst for One-Pot Friedlander Quinoline Synthesis [J].

Akbari, Jafar ;

Heydari, Akbar ;

Kalhor, Hamid Reza ;

Kohan, Sirus Azizian .

JOURNAL OF COMBINATORIAL CHEMISTRY, 2010, 12 (01) :137-140

[5] An investigation of the radiochemical stability of ionic liquids [J].

Allen, D ;

Baston, G ;

Bradley, AE ;

Gorman, T ;

Haile, A ;

Hamblett, I ;

Hatter, JE ;

Healey, MJF ;

Hodgson, B ;

Lewin, R ;

Lovell, KV ;

Newton, B ;

Pitner, WR ;

Rooney, DW ;

Sanders, D ;

Seddon, KR ;

Sims, HE ;

Thied, RC .

GREEN CHEMISTRY, 2002, 4 (02) :152-158

[6] Purification of ionic liquids by supercritical CO2 monitored by infrared spectroscopy [J].

Andanson, Jean-Michel ;

Jutz, Fabian ;

Baiker, Alfons .

JOURNAL OF SUPERCRITICAL FLUIDS, 2010, 55 (01) :395-400

[7] Structure and properties of high stability geminal dicationic ionic liquids [J].

Anderson, JL ;

Ding, RF ;

Ellern, A ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (02) :593-604

[8]

[Anonymous], 147 NIST

[9] Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes [J].

Aoyagi, Noboru ;

Shimojo, Kojiro ;

Brooks, Neil R. ;

Nagaishi, Ryuji ;

Naganawa, Hirochika ;

Van Hecke, Kristof ;

Van Meervelt, Luc ;

Binnemans, Koen ;

Kimura, Takaumi .

CHEMICAL COMMUNICATIONS, 2011, 47 (15) :4490-4492

[10]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

← 1 2 3 4 5 6 7 8 9 10 →