New polyfunctional spiropyran of 1,3-benzoxazin-4-one series with carbonyl-containing substituents in the [2H]-chromene moiety

被引：1

作者：

Ozhogin, I. V. ^{[1
]}

Tkachev, V. V. ^{[2
]}

Lukyanov, B. S. ^{[1
,3
]}

Shilov, G. V. ^{[2
]}

Mukhanov, E. L. ^{[1
]}

Vasilyuk, G. T. ^{[4
]}

Aldoshin, S. M. ^{[2
]}

Minkin, V. I. ^{[1
]}

机构：

[1] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

[3] Don State Tech Univ, Rostov Na Donu 344000, Russia

[4] Yanka Kupala State Univ, Grodno 230023, BELARUS

来源：

DOKLADY CHEMISTRY | 2017年 / 477卷

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0012500817110040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polyfunctional spiropyran of 1,3-benzoxazin-4-one series containing one hydroxy and two carbonyl substituents in the [2H]-chromene moiety was synthesized on the basis of a new analogue of 2,4-dihydroxyisophthalic aldehyde, methyl 3,5-diformyl-2,4-dihydroxybenzoate. The structure of resulting 6'-carbomethoxy-3,7-dimethyl-8'-formyl-5'-hydroxy-4-oxo-spiro-(1,3-benzoxazine-2,2'-[2H]-chromene) was unambiguously established by single crystal X-ray diffraction analysis. These data allowed us to reveal the route for the reaction of the new polyfunctional aldehyde with 1,3-benzoxazin-4-onium perchlorate.

引用

页码：244 / 247

页数：4

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