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Circularly Polarized Luminescence of Chiral Platinum(II) Complexes with Tetradentate Salen Ligands
被引:9
|作者:
Ikeshita, Masahiro
[1
]
Yamamoto, Takuho
[1
]
Watanabe, Shinya
[1
]
Kitahara, Maho
[2
]
Imai, Yoshitane
[2
]
Tsuno, Takashi
[1
]
机构:
[1] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Narashino, Chiba 2758575, Japan
[2] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan
关键词:
Circularly polarized luminescence
Schiff -base complex;
Platinum;
PHOSPHORESCENCE;
BASES;
D O I:
10.1246/cl.220224
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Chiral platinum(II) complexes with tetradentate salen ligands were synthesized, and characterized by NMR spectro-scopy and X-ray diffraction analysis. These complexes showed intense yellow and orange circularly polarized luminescence in N,N-dimethylformamide (DMF) solution state, and theoretical studies using density functional theory (DFT) and time depend-ent (TD)-DFT calculations revealed correlations between their structures and photophysical properties.
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页码:832 / 835
页数:4
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