Spectroscopic, Thermal Studies and Antimicrobial Activity of Nitrilotriacetates, (NTA)-Ce(III) and -Ce(VI) Complexes

被引：0
作者：
Gaballa, Akmal S. [1 ]
Teleb, Said M. [2 ]
Asker, Mohsen S. [3 ]
Soliman, Ahmed A. [4 ]
机构：
[1] Zagazig Univ, Fac Specif Educ, Zagazig, Egypt
[2] Zagazig Univ, Fac Sci, Dept Chem, Zagazig, Egypt
[3] Natl Res Ctr, Microbial Biotechnol Dept, Cairo, Egypt
[4] Cairo Univ, Fac Sci, Dept Chem, Giza, Egypt
来源：
ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 12期
关键词：
Nitrilotriacetic acid; Ce(III/IV) complexes; Kinetics of thermal decomposition; Antimicrobial activity; TERNARY COMPLEXES; INFRARED-SPECTRA; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURE; ACID; CERIUM(III); STABILITY; NTA; COORDINATION; NICKEL(II);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new complexes [Ce(NTA)(H2O)(2)] (1), H[Ce(NTA)(H2O)(2)]SO4 center dot 4H(2)O (2) were obtained during the reactions of metal salts CeCl3 center dot 7H(2)O and Ce(SO4)(2) with nitrilotriacetic acid, H(3)NTA. The infrared and H-1 NMR spectra of the solid complexes have been obtained and assigned. Thermogravimetry, differential thermal gravimetry and differential thermal analyses were also carried out. The data obtained agree quite well with the proposed structures and show that the complexes finally decompose to the corresponding cerium oxides and sulphate. The kinetics of thermal decomposition of the complexes have been studied. The complexes were screened for their antimicrobial activities by the agar-well diffusion technique using DMSO as a solvent against the E. coli, B. subtilis, P aereuguinosa, S. aureus and fungi: A. niger, A. fluves; C. albican and S. cervisiea. It has been found that the complexes show a considerable antimicrobial activity.
引用
收藏
页码：5343 / 5348
页数：6
相关论文
共 50 条
  • [31] Synthesis, Electrochemical, and Computational Studies of Organocerium(III) Complexes with Ce-Aryl Sigma Bonds
    Pandey, Pragati
    Yu, Xiaojuan
    Panetti, Grace B.
    Lapsheva, Ekaterina
    Gau, Michael R.
    Carroll, Patrick J.
    Autschbach, Jochen
    Schelter, Eric J.
    [J]. ORGANOMETALLICS, 2022, 42 (12) : 1267 - 1277
  • [32] Synthesis, spectroscopic, thermal, voltammetric studies and biological activity of crystalline complexes of pyridine-2,6-dicarboxylic acid and 8-hydroxyquinoline
    Colak, Alper Tolga
    Colak, Ferdag
    Yesilel, Okan Zafer
    Buyukgungor, Orhan
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2009, 936 (1-3) : 67 - 74
  • [33] Cu (II), Zn (II), and Ce (III) metal complexes as antimicrobial pigments for surface coating and flexographic ink
    Elsawy, M. M.
    Faheim, Abeer A.
    Salem, Salem S.
    Owda, M. E.
    Abd El-Wahab, Zeinab H.
    Abd El-Wahab, H.
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 35 (05)
  • [34] Synthesis, spectroscopic, thermogravimetric and antimicrobial studies of mixed ligands complexes
    Mahmoud, Walaa H.
    Mahmoud, Nessma F.
    Mohamed, Gehad G.
    El-Sonbati, Adel. Z.
    El-Bindary, Ashraf A.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2015, 1095 : 15 - 25
  • [35] Synthesis, characterization, spectroscopic and antimicrobial activity studies of pyrimidine dithiocarbamate macrocyclic complexes
    Nishat, N
    Rahis-ud-din
    Haq, MM
    [J]. POLISH JOURNAL OF CHEMISTRY, 2004, 78 (05) : 645 - 652
  • [36] Spectrophotometric and pH-Metric Studies of Ce(III), Dy(III), Gd(III), Yb(III) and Pr(III) Metal Complexes with Rifampicin
    Sonar, A. N.
    Pawar, N. S.
    [J]. E-JOURNAL OF CHEMISTRY, 2011, 8 (02) : 517 - 522
  • [37] Recent Studies on the Antimicrobial Activity of Copper Complexes
    O. A. Zalevskaya
    Y. A. Gur’eva
    [J]. Russian Journal of Coordination Chemistry, 2021, 47 : 861 - 880
  • [38] Synthesis, spectroscopic characterization, antimicrobial activity and crystal structure of silver and copper complexes of sulfamethazine
    Tailor, Sanjay M.
    Patel, Urmila H.
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (13) : 2192 - 2207
  • [39] SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY OF SOME NITRILOTRIACETIC ACID-V(III), -Sn(II), -Sm(II) AND -Sm(III) COMPLEXES
    Gaballa, Akmal S.
    Barakat, Atiat S.
    Teleb, Said M.
    Asker, Mohsen S.
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2011, 25 (01) : 61 - 71
  • [40] Metal complexes of phenylpiperazine-based dithiocarbamate ligands. Synthesis, characterization, spectroscopic, thermal, and antimicrobial activity studies
    Yilmaz, VT
    Yazicilar, TK
    Cesur, H
    Ozkanca, R
    Maras, FZ
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (04): : 589 - 605
12345