Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs

被引:46
|
作者
Smeacetto, F. [1 ]
Chrysanthou, A. [2 ]
Salvo, M. [1 ]
Moskalewicz, T. [3 ]
Bytner, F. D'Herin [4 ]
Ajitdoss, L. C. [1 ]
Ferraris, M. [1 ]
机构
[1] Politecn Torino, Dept Mat Sci & Chem Engn, I-10129 Turin, Italy
[2] Univ Hertfordshire, Sch Aerosp Automot & Design Engn, Hatfield AL10 9AB, Herts, England
[3] AGH Univ Sci & Technol, Fac Met Engn & Ind Comp Sci, PL-30059 Krakow, Poland
[4] St Gobain Isover CRIR, Rantigny, France
关键词
Glass-ceramic sealant; Solid oxide fuel cell; Trasmission electron microscopy; Microstructure; Crofer22APU; SILICATE SEALING GLASS; STAINLESS-STEEL; COMPOSITE SEALS; OXIDE; ALLOY; INTERCONNECT; STABILITY; YSZ; COMPATIBILITY; ELECTROLYTE;
D O I
10.1016/j.ijhydene.2011.04.083
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermal cycling and thermal ageing tests were performed on Crofer22APU/glass-ceramic/Anode-Supported-Electrolyte (ASE) joined samples in air at the SOFC operating temperature of 800 degrees C. The Crofer22APU had been polished and preoxidised at 900 degrees C for 2 h. The diffusion behaviour at the two interfaces was examined and revealed slight diffusion of chromium and manganese from Crofer22APU into the glass-ceramic. No interactions, failure or crack formation were observed at the Crofer22APU/glass-ceramic interface and between the glass-ceramic and YSZ. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:11895 / 11903
页数:9
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