Nitrogen-Rich Azoles as Ligand Spacers in Coordination Polymers

被引：71
作者：
Bai, Shi-Qiang [1 ]
Young, David J. [3 ]
Hor, T. S. Andy [1 ,2 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore
[3] Univ Brunei Darussalam, Fac Sci, BE-1410 Gadong, Brunei Darussal, Brunei
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 02期
关键词：
azoles; coordination polymers; nitrogen heterocycles; oligomers; supramolecules; METAL-ORGANIC FRAMEWORKS; TRINUCLEAR COPPER(II) COMPLEX; ANION-EXCHANGE PROPERTIES; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; TRIPODAL LIGAND; SPIN-CROSSOVER; HYDROGEN STORAGE;
D O I：
10.1002/asia.201000698
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-heterocycle-based ligands are versatile building-blocks for coordination oligomer and polymer assemblies of first-row transition metals. Herein, we review recent developments in the design and synthesis of some nitrogen-rich azole-based ligands, their assembly modes in coordination oligomers and polymers, and the potential applications of the resulting metallosupramolecules.
引用
收藏
页码：292 / 304
页数：13
相关论文
共 163 条
  • [71] Huisgen R., 1968, ANGEW CHEM, V80, P329
  • [72] Rational design of metal-organic frameworks based on 5-(4-pyridyl)tetrazolate: From 2D grids to 3D porous networks
    Jiang, C
    Yu, ZP
    Wang, SJ
    Jiao, C
    Li, JM
    Wang, ZY
    Cui, Y
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (18) : 3662 - 3667
  • [73] Temperature tuned synthesis of zinc N,N-bis-(1(2)H-tetrazol-5-yl)-aniine complexes:: from Zn3O cluster-based 3-connected 63-hcb and (3,6)-connected (43)2(46)-kgd layers to Zn5(OH)4 chain-based 3D open framework
    Jiang, Tao
    Zhang, Xian-Ming
    [J]. CRYSTAL GROWTH & DESIGN, 2008, 8 (08) : 3077 - 3083
  • [74] An Unusual Three-Dimensional Water Cluster in Metal-Organic Frameworks Based on ZnX2(X = ClC4, BF4) and an Azo-Functional Ligand
    Jin, Chuan-Ming
    Zhu, Zhu
    Chen, Zhan-Fen
    Hu, Yan-Jun
    Meng, Xiang-Gao
    [J]. CRYSTAL GROWTH & DESIGN, 2010, 10 (05) : 2054 - 2056
  • [75] Joule J.A., 2000, HETEROCYCLIC CHEM, V4th
  • [76] Kantchev E.A. B., 2007, ANGEW CHEM, V119, P2824
  • [77] Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions - A synthetic chemist's perspective
    Kantchev, Eric Assen B.
    O'Brien, Christopher J.
    Organ, Michael G.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (16) : 2768 - 2813
  • [78] Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3-triazole "click" ligands: Synthesis, properties and X-ray structures
    Kilpin, Kelly J.
    Crowley, James D.
    [J]. POLYHEDRON, 2010, 29 (16) : 3111 - 3117
  • [79] Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates
    Kitchen, Jonathan A.
    Brooker, Sally
    [J]. COORDINATION CHEMISTRY REVIEWS, 2008, 252 (18-20) : 2072 - 2092
  • [80] Spin crossover in co-crystallised 2: 1 cis : trans [FeII(pldpt)2(NCS)2] occurs only in 1/3 of the iron centres
    Kitchen, Jonathan A.
    Jameson, Guy N. L.
    Tallon, Jeffery L.
    Brooker, Sally
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (18) : 3200 - 3202
3456789101112