Nitrogen-Rich Azoles as Ligand Spacers in Coordination Polymers

被引：71

作者：

Bai, Shi-Qiang ^{[1
]}

Young, David J. ^{[3
]}

Hor, T. S. Andy ^{[1
,2
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore

[3] Univ Brunei Darussalam, Fac Sci, BE-1410 Gadong, Brunei Darussal, Brunei

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 02期

关键词：

azoles; coordination polymers; nitrogen heterocycles; oligomers; supramolecules; METAL-ORGANIC FRAMEWORKS; TRINUCLEAR COPPER(II) COMPLEX; ANION-EXCHANGE PROPERTIES; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; TRIPODAL LIGAND; SPIN-CROSSOVER; HYDROGEN STORAGE;

D O I：

10.1002/asia.201000698

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-heterocycle-based ligands are versatile building-blocks for coordination oligomer and polymer assemblies of first-row transition metals. Herein, we review recent developments in the design and synthesis of some nitrogen-rich azole-based ligands, their assembly modes in coordination oligomers and polymers, and the potential applications of the resulting metallosupramolecules.

引用

页码：292 / 304

页数：13

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